[PtMe(iPr3P)(2)](+): a Pt(II) complex with an agostic interaction that undergoes C-H activation

M J Ingleson; M F Mahon; A S Weller

doi:10.1039/b410846a

[PtMe(iPr3P)(2)](+): a Pt(II) complex with an agostic interaction that undergoes C-H activation

M J Ingleson, M F Mahon, A S Weller

Department of Chemistry

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80 Citations (SciVal)

Abstract

The T-shaped Pt(II) complex [PtMe((Pr3P)-Pr-i)(2)][1-H-closo-CB11Me11], which is stabilised by an agostic interaction, undergoes acid-catalysed intramolecular C-H activation in the presence of THF to afford cyclometallated [Pt(THF)((Pr3P)-Pr-i)((Pr2PCHMeCH2)-Pr-i)][1-H-closo-CB11Me11].

Original language	English
Pages (from-to)	2398-2399
Number of pages	2
Journal	Chemical Communications
Issue number	21
DOIs	https://doi.org/10.1039/b410846a
Publication status	Published - 2004

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ID number: ISI:000224755600013

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10.1039/b410846a

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title = "[PtMe(iPr3P)(2)](+): a Pt(II) complex with an agostic interaction that undergoes C-H activation",

abstract = "The T-shaped Pt(II) complex [PtMe((Pr3P)-Pr-i)(2)][1-H-closo-CB11Me11], which is stabilised by an agostic interaction, undergoes acid-catalysed intramolecular C-H activation in the presence of THF to afford cyclometallated [Pt(THF)((Pr3P)-Pr-i)((Pr2PCHMeCH2)-Pr-i)][1-H-closo-CB11Me11].",

author = "Ingleson, {M J} and Mahon, {M F} and Weller, {A S}",

note = "ID number: ISI:000224755600013",

year = "2004",

doi = "10.1039/b410846a",

language = "English",

pages = "2398--2399",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "21",

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T1 - [PtMe(iPr3P)(2)](+): a Pt(II) complex with an agostic interaction that undergoes C-H activation

AU - Ingleson, M J

AU - Mahon, M F

AU - Weller, A S

N1 - ID number: ISI:000224755600013

PY - 2004

Y1 - 2004

N2 - The T-shaped Pt(II) complex [PtMe((Pr3P)-Pr-i)(2)][1-H-closo-CB11Me11], which is stabilised by an agostic interaction, undergoes acid-catalysed intramolecular C-H activation in the presence of THF to afford cyclometallated [Pt(THF)((Pr3P)-Pr-i)((Pr2PCHMeCH2)-Pr-i)][1-H-closo-CB11Me11].

AB - The T-shaped Pt(II) complex [PtMe((Pr3P)-Pr-i)(2)][1-H-closo-CB11Me11], which is stabilised by an agostic interaction, undergoes acid-catalysed intramolecular C-H activation in the presence of THF to afford cyclometallated [Pt(THF)((Pr3P)-Pr-i)((Pr2PCHMeCH2)-Pr-i)][1-H-closo-CB11Me11].

U2 - 10.1039/b410846a

DO - 10.1039/b410846a

M3 - Article

SN - 1359-7345

SP - 2398

EP - 2399

JO - Chemical Communications

JF - Chemical Communications

IS - 21

ER -

[PtMe(iPr3P)(2)](+): a Pt(II) complex with an agostic interaction that undergoes C-H activation

Abstract

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