[PtMe(iPr3P)(2)](+): a Pt(II) complex with an agostic interaction that undergoes C-H activation

M J Ingleson, M F Mahon, A S Weller

Research output: Contribution to journalArticle

78 Citations (Scopus)

Abstract

The T-shaped Pt(II) complex [PtMe((Pr3P)-Pr-i)(2)][1-H-closo-CB11Me11], which is stabilised by an agostic interaction, undergoes acid-catalysed intramolecular C-H activation in the presence of THF to afford cyclometallated [Pt(THF)((Pr3P)-Pr-i)((Pr2PCHMeCH2)-Pr-i)][1-H-closo-CB11Me11].
Original languageEnglish
Pages (from-to)2398-2399
Number of pages2
JournalChemical Communications
Issue number21
DOIs
Publication statusPublished - 2004

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