Preparation of Copper Organometallics via Nucleophilic Substitution of CpCuPPh₃: Syntheses and X-ray Structure Determinations of [Li(THF)₄]⁺[(fluorenyl)₂CuPPh₃]^- and [Cy₃PCu(μ-C≡C^tBu)₂Cu(PPh₃)₂] (THF = Tetrahydrofuran, Fluorenyl = C₁₃H₉)

Andrew J. Edwards, Michael A. Paver, Paul R. Raithby, Moira Ann Rennie, Christopher A. Russell, Dominic S. Wright

Department of Life Sciences
Centre for Sustainable Chemical Technologies (CSCT)
Centre for Nanoscience and Nanotechnology
Department of Chemistry

University of Cambridge

Research output: Contribution to journal › Article › peer-review

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Preparation of Copper Organometallics via Nucleophilic Substitution of CpCuPPh3: Syntheses and X-ray Structure Determinations of [Li(THF)4]+[(fluorenyl)2CuPPh3]- and [Cy3PCu(μ-C≡CtBu)2Cu(PPh3)2] (THF = Tetrahydrofuran, Fluorenyl = C13H9)

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Chemistry

Preparation of Copper Organometallics via Nucleophilic Substitution of CpCuPPh₃: Syntheses and X-ray Structure Determinations of [Li(THF)₄]⁺[(fluorenyl)₂CuPPh₃]^- and [Cy₃PCu(μ-C≡C^tBu)₂Cu(PPh₃)₂] (THF = Tetrahydrofuran, Fluorenyl = C₁₃H₉)