Preparation and characterisation of some mixed clusters of bismuth with osmium and ruthenium; crystal and molecular structures of...

H. G. Ang; Caroline M. Hay; Brian F.G. Johnson; Jack Lewis; Paul R. Raithby; Alan J. Whitton

doi:10.1016/0022-328X(87)80298-X

Preparation and characterisation of some mixed clusters of bismuth with osmium and ruthenium; crystal and molecular structures of...

H. G. Ang, Caroline M. Hay, Brian F.G. Johnson, Jack Lewis, Paul R. Raithby, Alan J. Whitton

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

Title full: Preparation and characterisation of some mixed clusters of bismuth with osmium and ruthenium; crystal and molecular structures of Os₃(μ-H)₃(CO)₉(μ₃-Bi), Os₄(CO)₁₂(μ₄-Bi)₂, Ru₃(μ-H)₃(CO)₉(μ₃-Bi), and Ru₄(CO)₁₂(μ₄-Bi)₂. Reaction of NaBiO₃ with Os₃(CO)₁₂ and a number of higher nuclearity osmium clusters affords a variety of bismuth-containing products, including Os₃H₃(CO)₉Bi (1), Os₃(CO)₉Bi₂ (2), and Os₄(CO)₁₂Bi₂ (3). Under similar conditions, Ru₃(CO)₁₂ affords only low yields of Ru₃H₃(CO)₉Bi (5), but better yields of Ru₃H₃(CO)₉Bi (5), Ru₃(CO)₉Bi₂ (6), Ru₄(CO)₁₂Bi₂ (7), and Ru₅H(CO)₁₈Bi (8), are obtained by reaction of Bi(NO₃)₃ · 5H₂O with the [Ru₃H(CO)₁₁]^- anion. The structures of 1, 3, 5, and 7 have been established by X-ray diffraction; 1 and 5 are isostructural with the known iron analogue, while the metal frameworks in 3 and 7 display different isomeric forms of the M₄Bi₂ octahedron.

Original language	English
Pages (from-to)	C5-C11
Journal	Journal of Organometallic Chemistry
Volume	330
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(87)80298-X
Publication status	Published - 18 Aug 1987

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0022-328X(87)80298-X

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@article{891fec1f7af148ac9e6f67d4a320abeb,

title = "Preparation and characterisation of some mixed clusters of bismuth with osmium and ruthenium; crystal and molecular structures of...",

abstract = "Title full: Preparation and characterisation of some mixed clusters of bismuth with osmium and ruthenium; crystal and molecular structures of Os3(μ-H)3(CO)9(μ3-Bi), Os4(CO)12(μ4-Bi)2, Ru3(μ-H)3(CO)9(μ3-Bi), and Ru4(CO)12(μ4-Bi)2. Reaction of NaBiO3 with Os3(CO)12 and a number of higher nuclearity osmium clusters affords a variety of bismuth-containing products, including Os3H3(CO)9Bi (1), Os3(CO)9Bi2 (2), and Os4(CO)12Bi2 (3). Under similar conditions, Ru3(CO)12 affords only low yields of Ru3H3(CO)9Bi (5), but better yields of Ru3H3(CO)9Bi (5), Ru3(CO)9Bi2 (6), Ru4(CO)12Bi2 (7), and Ru5H(CO)18Bi (8), are obtained by reaction of Bi(NO3)3 · 5H2O with the [Ru3H(CO)11]- anion. The structures of 1, 3, 5, and 7 have been established by X-ray diffraction; 1 and 5 are isostructural with the known iron analogue, while the metal frameworks in 3 and 7 display different isomeric forms of the M4Bi2 octahedron.",

author = "Ang, {H. G.} and Hay, {Caroline M.} and Johnson, {Brian F.G.} and Jack Lewis and Raithby, {Paul R.} and Whitton, {Alan J.}",

year = "1987",

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AU - Ang, H. G.

AU - Hay, Caroline M.

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Raithby, Paul R.

AU - Whitton, Alan J.

PY - 1987/8/18

Y1 - 1987/8/18

N2 - Title full: Preparation and characterisation of some mixed clusters of bismuth with osmium and ruthenium; crystal and molecular structures of Os3(μ-H)3(CO)9(μ3-Bi), Os4(CO)12(μ4-Bi)2, Ru3(μ-H)3(CO)9(μ3-Bi), and Ru4(CO)12(μ4-Bi)2. Reaction of NaBiO3 with Os3(CO)12 and a number of higher nuclearity osmium clusters affords a variety of bismuth-containing products, including Os3H3(CO)9Bi (1), Os3(CO)9Bi2 (2), and Os4(CO)12Bi2 (3). Under similar conditions, Ru3(CO)12 affords only low yields of Ru3H3(CO)9Bi (5), but better yields of Ru3H3(CO)9Bi (5), Ru3(CO)9Bi2 (6), Ru4(CO)12Bi2 (7), and Ru5H(CO)18Bi (8), are obtained by reaction of Bi(NO3)3 · 5H2O with the [Ru3H(CO)11]- anion. The structures of 1, 3, 5, and 7 have been established by X-ray diffraction; 1 and 5 are isostructural with the known iron analogue, while the metal frameworks in 3 and 7 display different isomeric forms of the M4Bi2 octahedron.

AB - Title full: Preparation and characterisation of some mixed clusters of bismuth with osmium and ruthenium; crystal and molecular structures of Os3(μ-H)3(CO)9(μ3-Bi), Os4(CO)12(μ4-Bi)2, Ru3(μ-H)3(CO)9(μ3-Bi), and Ru4(CO)12(μ4-Bi)2. Reaction of NaBiO3 with Os3(CO)12 and a number of higher nuclearity osmium clusters affords a variety of bismuth-containing products, including Os3H3(CO)9Bi (1), Os3(CO)9Bi2 (2), and Os4(CO)12Bi2 (3). Under similar conditions, Ru3(CO)12 affords only low yields of Ru3H3(CO)9Bi (5), but better yields of Ru3H3(CO)9Bi (5), Ru3(CO)9Bi2 (6), Ru4(CO)12Bi2 (7), and Ru5H(CO)18Bi (8), are obtained by reaction of Bi(NO3)3 · 5H2O with the [Ru3H(CO)11]- anion. The structures of 1, 3, 5, and 7 have been established by X-ray diffraction; 1 and 5 are isostructural with the known iron analogue, while the metal frameworks in 3 and 7 display different isomeric forms of the M4Bi2 octahedron.

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Preparation and characterisation of some mixed clusters of bismuth with osmium and ruthenium; crystal and molecular structures of...

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