Postsynthetic bromination of UiO-66 analogues: Altering linker flexibility and mechanical compliance

Ross J. Marshall; Tom Richards; Claire L. Hobday; Colin F. Murphie; Claire Wilson; Stephen A. Moggach; Thomas D. Bennett; Ross S. Forgan

doi:10.1039/c5dt03178h

Postsynthetic bromination of UiO-66 analogues: Altering linker flexibility and mechanical compliance

Ross J. Marshall, Tom Richards, Claire L. Hobday, Colin F. Murphie, Claire Wilson, Stephen A. Moggach, Thomas D. Bennett, Ross S. Forgan

Research output: Contribution to journal › Article › peer-review

37 Citations (SciVal)

Abstract

A new member of the UiO-66 series of zirconium metal-organic frameworks (MOFs) is reported, and the postsynthetic bromination of its integral alkene moeities in a single-crystal to single-crystal manner is fully characterised. Nanoindentation is used to probe the bromination of unsaturated carbon-carbon bonds, in it and an analogous Zr MOF, which leads to more compliant materials with lower elastic moduli.

Original language	English
Pages (from-to)	4132-4135
Number of pages	4
Journal	Dalton Transactions
Volume	45
Issue number	10
Early online date	11 Nov 2015
DOIs	https://doi.org/10.1039/c5dt03178h
Publication status	Published - 14 Mar 2016

Funding

RSF thanks the Royal Society for receipt of a University Research Fellowship, and the University of Glasgow and EPSRC (EP/L004461/1) for funding. RSF, TDB and SAM gratefully acknowledge pump-priming funding from the EPSRC Directed Assembly Network (PP 14 05 03). TDB thanks Trinity Hall (University of Cambridge) for funding. We thank the EPSRC UK National Crystallographic Service for single crystal data collection for (2-Br2). 23 The data which underpin this work are available at http://dx.doi.org/10.5525/gla.researchdata.231. CCDC 1418959-1418961 contain the supplementary crystallographic data for this paper.

ASJC Scopus subject areas

Inorganic Chemistry

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Postsynthetic bromination of UiO-66 analogues: Altering linker flexibility and mechanical compliance

Abstract

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