Postsynthetic bromination of UiO-66 analogues: Altering linker flexibility and mechanical compliance

Ross J. Marshall; Tom Richards; Claire L. Hobday; Colin F. Murphie; Claire Wilson; Stephen A. Moggach; Thomas D. Bennett; Ross S. Forgan

doi:10.1039/c5dt03178h

Postsynthetic bromination of UiO-66 analogues: Altering linker flexibility and mechanical compliance

Ross J. Marshall, Tom Richards, Claire L. Hobday, Colin F. Murphie, Claire Wilson, Stephen A. Moggach, Thomas D. Bennett, Ross S. Forgan

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35 Citations (SciVal)

Abstract

A new member of the UiO-66 series of zirconium metal-organic frameworks (MOFs) is reported, and the postsynthetic bromination of its integral alkene moeities in a single-crystal to single-crystal manner is fully characterised. Nanoindentation is used to probe the bromination of unsaturated carbon-carbon bonds, in it and an analogous Zr MOF, which leads to more compliant materials with lower elastic moduli.

Original language	English
Pages (from-to)	4132-4135
Number of pages	4
Journal	Dalton Transactions
Volume	45
Issue number	10
Early online date	11 Nov 2015
DOIs	https://doi.org/10.1039/c5dt03178h
Publication status	Published - 14 Mar 2016

ASJC Scopus subject areas

Inorganic Chemistry

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AU - Marshall, Ross J.

AU - Richards, Tom

AU - Hobday, Claire L.

AU - Murphie, Colin F.

AU - Wilson, Claire

AU - Moggach, Stephen A.

AU - Bennett, Thomas D.

AU - Forgan, Ross S.

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AB - A new member of the UiO-66 series of zirconium metal-organic frameworks (MOFs) is reported, and the postsynthetic bromination of its integral alkene moeities in a single-crystal to single-crystal manner is fully characterised. Nanoindentation is used to probe the bromination of unsaturated carbon-carbon bonds, in it and an analogous Zr MOF, which leads to more compliant materials with lower elastic moduli.

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Postsynthetic bromination of UiO-66 analogues: Altering linker flexibility and mechanical compliance

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