Post-synthetic modification of zinc metal-organic frameworks through palladium-catalysed carbon-carbon bond formation

Andrew D. Burrows; Laura C. Fisher; Timothy J. Mays; Sean P. Rigby; Sharon E. Ashbrook; Daniel M. Dawson

doi:10.1016/j.jorganchem.2015.03.031

Post-synthetic modification of zinc metal-organic frameworks through palladium-catalysed carbon-carbon bond formation

Andrew D. Burrows, Laura C. Fisher, Timothy J. Mays, Sean P. Rigby, Sharon E. Ashbrook, Daniel M. Dawson

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Abstract

Post-synthetic Suzuki coupling reactions have been undertaken on the halide-functionalised metal-organic frameworks (MOFs) [Zn₄O(bdc-Br)₃] (bdc-Br = 2-bromo-1,4-benzenedicarboxylate, IRMOF-2) and [Zn₄O(bdc-I)₃] (bdc-I = 2-iodo-1,4-benzenedicarboxylate). Although the bulky catalyst employed leads to relatively low conversions, the use of core-shell MOFs demonstrates that the reactions are not confined to the crystal surfaces.

Original language	English
Pages (from-to)	134-138
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	792
Early online date	9 Apr 2015
DOIs	https://doi.org/10.1016/j.jorganchem.2015.03.031
Publication status	Published - 1 Sep 2015

Keywords

Metal-organic framework
Palladium
Post-synthetic modification
Suzuki coupling
Zinc

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10.1016/j.jorganchem.2015.03.031

fisher-msv2Accepted author manuscript, 1.89 MBLicence: CC BY-NC-ND

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title = "Post-synthetic modification of zinc metal-organic frameworks through palladium-catalysed carbon-carbon bond formation",

abstract = "Post-synthetic Suzuki coupling reactions have been undertaken on the halide-functionalised metal-organic frameworks (MOFs) [Zn4O(bdc-Br)3] (bdc-Br = 2-bromo-1,4-benzenedicarboxylate, IRMOF-2) and [Zn4O(bdc-I)3] (bdc-I = 2-iodo-1,4-benzenedicarboxylate). Although the bulky catalyst employed leads to relatively low conversions, the use of core-shell MOFs demonstrates that the reactions are not confined to the crystal surfaces.",

keywords = "Metal-organic framework, Palladium, Post-synthetic modification, Suzuki coupling, Zinc",

author = "Burrows, {Andrew D.} and Fisher, {Laura C.} and Mays, {Timothy J.} and Rigby, {Sean P.} and Ashbrook, {Sharon E.} and Dawson, {Daniel M.}",

year = "2015",

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day = "1",

doi = "10.1016/j.jorganchem.2015.03.031",

language = "English",

volume = "792",

pages = "134--138",

journal = "Journal of Organometallic Chemistry",

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TY - JOUR

T1 - Post-synthetic modification of zinc metal-organic frameworks through palladium-catalysed carbon-carbon bond formation

AU - Burrows, Andrew D.

AU - Fisher, Laura C.

AU - Mays, Timothy J.

AU - Rigby, Sean P.

AU - Ashbrook, Sharon E.

AU - Dawson, Daniel M.

PY - 2015/9/1

Y1 - 2015/9/1

N2 - Post-synthetic Suzuki coupling reactions have been undertaken on the halide-functionalised metal-organic frameworks (MOFs) [Zn4O(bdc-Br)3] (bdc-Br = 2-bromo-1,4-benzenedicarboxylate, IRMOF-2) and [Zn4O(bdc-I)3] (bdc-I = 2-iodo-1,4-benzenedicarboxylate). Although the bulky catalyst employed leads to relatively low conversions, the use of core-shell MOFs demonstrates that the reactions are not confined to the crystal surfaces.

AB - Post-synthetic Suzuki coupling reactions have been undertaken on the halide-functionalised metal-organic frameworks (MOFs) [Zn4O(bdc-Br)3] (bdc-Br = 2-bromo-1,4-benzenedicarboxylate, IRMOF-2) and [Zn4O(bdc-I)3] (bdc-I = 2-iodo-1,4-benzenedicarboxylate). Although the bulky catalyst employed leads to relatively low conversions, the use of core-shell MOFs demonstrates that the reactions are not confined to the crystal surfaces.

KW - Metal-organic framework

KW - Palladium

KW - Post-synthetic modification

KW - Suzuki coupling

KW - Zinc

UR - http://www.scopus.com/inward/record.url?scp=84938968793&partnerID=8YFLogxK

UR - http://dx.doi.org/10.1016/j.jorganchem.2015.03.031

U2 - 10.1016/j.jorganchem.2015.03.031

DO - 10.1016/j.jorganchem.2015.03.031

M3 - Article

AN - SCOPUS:84938968793

VL - 792

SP - 134

EP - 138

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

ER -

Post-synthetic modification of zinc metal-organic frameworks through palladium-catalysed carbon-carbon bond formation

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