Abstract
Post-synthetic Suzuki coupling reactions have been undertaken on the halide-functionalised metal-organic frameworks (MOFs) [Zn4O(bdc-Br)3] (bdc-Br = 2-bromo-1,4-benzenedicarboxylate, IRMOF-2) and [Zn4O(bdc-I)3] (bdc-I = 2-iodo-1,4-benzenedicarboxylate). Although the bulky catalyst employed leads to relatively low conversions, the use of core-shell MOFs demonstrates that the reactions are not confined to the crystal surfaces.
Original language | English |
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Pages (from-to) | 134-138 |
Number of pages | 5 |
Journal | Journal of Organometallic Chemistry |
Volume | 792 |
Early online date | 9 Apr 2015 |
DOIs | |
Publication status | Published - 1 Sept 2015 |
Keywords
- Metal-organic framework
- Palladium
- Post-synthetic modification
- Suzuki coupling
- Zinc
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Electrospray Time-of-Flight Mass Spectrometer (Open-Access)
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