Polynuclear Complexes as Precursor Templates for Hierarchical Microporous Graphitic Carbon: An Unusual Approach

Paulina A. Kobielska; Richard Telford; Jemma Rowlandson; Mi Tian; Zahraa Shahin; Aude Demessence; Valeska P. Ting; Sanjit Nayak

doi:10.1021/acsami.8b10149

Polynuclear Complexes as Precursor Templates for Hierarchical Microporous Graphitic Carbon: An Unusual Approach

Paulina A. Kobielska, Richard Telford, Jemma Rowlandson, Mi Tian, Zahraa Shahin, Aude Demessence, Valeska P. Ting, Sanjit Nayak

Research output: Contribution to journal › Article › peer-review

6 Citations (SciVal)

Abstract

A highly porous carbon was synthesized using a coordination complex as an unusual precursor. During controlled pyrolysis, a trinuclear copper complex, [Cu^II ₃Cl₄(H₂L)₂]·CH₃OH, undergoes phase changes with melt and expulsion of different gases to produce a unique morphology of copper-doped carbon which, upon acid treatment, produces highly porous graphitic carbon with a surface area of 857 m² g^-1 and a gravimetric hydrogen uptake of 1.1 wt % at 0.5 bar pressure at 77 K.

Original language	English
Pages (from-to)	25967-25971
Number of pages	5
Journal	ACS Applied Materials and Interfaces
Volume	10
Issue number	31
Early online date	17 Jul 2018
DOIs	https://doi.org/10.1021/acsami.8b10149
Publication status	Published - 8 Aug 2018

Keywords

complex-derived carbon
coordination complex
graphitic carbon
hydrogen storage
polynuclear complex
porous carbon
template precursor

ASJC Scopus subject areas

Materials Science(all)

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10.1021/acsami.8b10149

https://bradscholars.brad.ac.uk/handle/10454/16535

Cite this

Polynuclear Complexes as Precursor Templates for Hierarchical Microporous Graphitic Carbon : An Unusual Approach. / Kobielska, Paulina A.; Telford, Richard; Rowlandson, Jemma; Tian, Mi; Shahin, Zahraa; Demessence, Aude; Ting, Valeska P.; Nayak, Sanjit.

In: ACS Applied Materials and Interfaces, Vol. 10, No. 31, 08.08.2018, p. 25967-25971.

Research output: Contribution to journal › Article › peer-review

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abstract = "A highly porous carbon was synthesized using a coordination complex as an unusual precursor. During controlled pyrolysis, a trinuclear copper complex, [CuII 3Cl4(H2L)2]·CH3OH, undergoes phase changes with melt and expulsion of different gases to produce a unique morphology of copper-doped carbon which, upon acid treatment, produces highly porous graphitic carbon with a surface area of 857 m2 g-1 and a gravimetric hydrogen uptake of 1.1 wt % at 0.5 bar pressure at 77 K.",

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author = "Kobielska, {Paulina A.} and Richard Telford and Jemma Rowlandson and Mi Tian and Zahraa Shahin and Aude Demessence and Ting, {Valeska P.} and Sanjit Nayak",

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T1 - Polynuclear Complexes as Precursor Templates for Hierarchical Microporous Graphitic Carbon

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AU - Kobielska, Paulina A.

AU - Telford, Richard

AU - Rowlandson, Jemma

AU - Tian, Mi

AU - Shahin, Zahraa

AU - Demessence, Aude

AU - Ting, Valeska P.

AU - Nayak, Sanjit

PY - 2018/8/8

Y1 - 2018/8/8

N2 - A highly porous carbon was synthesized using a coordination complex as an unusual precursor. During controlled pyrolysis, a trinuclear copper complex, [CuII 3Cl4(H2L)2]·CH3OH, undergoes phase changes with melt and expulsion of different gases to produce a unique morphology of copper-doped carbon which, upon acid treatment, produces highly porous graphitic carbon with a surface area of 857 m2 g-1 and a gravimetric hydrogen uptake of 1.1 wt % at 0.5 bar pressure at 77 K.

AB - A highly porous carbon was synthesized using a coordination complex as an unusual precursor. During controlled pyrolysis, a trinuclear copper complex, [CuII 3Cl4(H2L)2]·CH3OH, undergoes phase changes with melt and expulsion of different gases to produce a unique morphology of copper-doped carbon which, upon acid treatment, produces highly porous graphitic carbon with a surface area of 857 m2 g-1 and a gravimetric hydrogen uptake of 1.1 wt % at 0.5 bar pressure at 77 K.

KW - complex-derived carbon

KW - coordination complex

KW - graphitic carbon

KW - hydrogen storage

KW - polynuclear complex

KW - porous carbon

KW - template precursor

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JO - ACS Applied Materials and Interfaces

JF - ACS Applied Materials and Interfaces

SN - 1944-8244

IS - 31

ER -

Polynuclear Complexes as Precursor Templates for Hierarchical Microporous Graphitic Carbon: An Unusual Approach

Abstract

Keywords

ASJC Scopus subject areas

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