Polynuclear clusters of fused-ring hydrocarbons. The synthesis and X-ray structure of [Os4H(CO)93- η225-C13H 15)] (C13H15 = 1,3-diethylindenyl)

Jack Lewis, Paul R. Raithby, Gregory N. Ward

Research output: Contribution to journalArticlepeer-review

Abstract

The reaction between [Os3(CO)12] and 1,3-diethylindene yields [Os4H(CO)93- η225-C13H 15)], the structure of which is shown by X-ray crystallography to consist of a distorted tetrahedral metal framework with one triangular face coordinated by the indenyl such that the six membered ring is in the μ3222 face capping mode whilst the five membered ring is η5-bound to one of the Os atoms.

Original languageEnglish
Pages (from-to)755-756
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Volume1995
Issue number7
DOIs
Publication statusPublished - 31 Dec 1995

ASJC Scopus subject areas

  • Molecular Medicine

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