Polynuclear clusters of fused-ring hydrocarbons. The synthesis and X-ray structure of [Os4H(CO)9(μ3- η2-η2-η5-C13H 15)] (C13H15 = 1,3-diethylindenyl)

Jack Lewis; Paul R. Raithby; Gregory N. Ward

doi:10.1039/C39950000755

Polynuclear clusters of fused-ring hydrocarbons. The synthesis and X-ray structure of [Os₄H(CO)₉(μ₃- η²-η²-η⁵-C₁₃H ₁₅)] (C₁₃H₁₅ = 1,3-diethylindenyl)

Jack Lewis, Paul R. Raithby, Gregory N. Ward

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction between [Os₃(CO)₁₂] and 1,3-diethylindene yields [Os₄H(CO)₉(μ₃- η²-η²-η⁵-C₁₃H ₁₅)], the structure of which is shown by X-ray crystallography to consist of a distorted tetrahedral metal framework with one triangular face coordinated by the indenyl such that the six membered ring is in the μ³-η²-η²-η² face capping mode whilst the five membered ring is η⁵-bound to one of the Os atoms.

Original language	English
Pages (from-to)	755-756
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Volume	1995
Issue number	7
DOIs	https://doi.org/10.1039/C39950000755
Publication status	Published - 31 Dec 1995

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Molecular Medicine

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10.1039/C39950000755

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Polynuclear clusters of fused-ring hydrocarbons. The synthesis and X-ray structure of [Os₄H(CO)₉(μ₃- η²-η²-η⁵-C₁₃H ₁₅)] (C₁₃H₁₅ = 1,3-diethylindenyl). / Lewis, Jack; Raithby, Paul R.; Ward, Gregory N.
In: Journal of the Chemical Society, Chemical Communications, Vol. 1995, No. 7, 31.12.1995, p. 755-756.

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abstract = "The reaction between [Os3(CO)12] and 1,3-diethylindene yields [Os4H(CO)9(μ3- η2-η2-η5-C13H 15)], the structure of which is shown by X-ray crystallography to consist of a distorted tetrahedral metal framework with one triangular face coordinated by the indenyl such that the six membered ring is in the μ3-η2-η2-η2 face capping mode whilst the five membered ring is η5-bound to one of the Os atoms.",

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AU - Raithby, Paul R.

AU - Ward, Gregory N.

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N2 - The reaction between [Os3(CO)12] and 1,3-diethylindene yields [Os4H(CO)9(μ3- η2-η2-η5-C13H 15)], the structure of which is shown by X-ray crystallography to consist of a distorted tetrahedral metal framework with one triangular face coordinated by the indenyl such that the six membered ring is in the μ3-η2-η2-η2 face capping mode whilst the five membered ring is η5-bound to one of the Os atoms.

AB - The reaction between [Os3(CO)12] and 1,3-diethylindene yields [Os4H(CO)9(μ3- η2-η2-η5-C13H 15)], the structure of which is shown by X-ray crystallography to consist of a distorted tetrahedral metal framework with one triangular face coordinated by the indenyl such that the six membered ring is in the μ3-η2-η2-η2 face capping mode whilst the five membered ring is η5-bound to one of the Os atoms.

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Polynuclear clusters of fused-ring hydrocarbons. The synthesis and X-ray structure of [Os₄H(CO)₉(μ₃- η²-η²-η⁵-C₁₃H ₁₅)] (C₁₃H₁₅ = 1,3-diethylindenyl)

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