Polymers of Intrinsic Microporosity (PIMs) in Sensing and in Electroanalysis

Frank Marken; Lina Wang; Yuanzhu Zhao; Zhongkai Li; Mandana Amiri; Hamideh Imanzadeh

doi:10.1016/j.coche.2021.100765

Polymers of Intrinsic Microporosity (PIMs) in Sensing and in Electroanalysis

Frank Marken, Lina Wang, Yuanzhu Zhao, Zhongkai Li, Mandana Amiri, Hamideh Imanzadeh

University of Mohaghegh Ardabili

Research output: Contribution to journal › Review article › peer-review

11 Citations (SciVal)

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Abstract

Polymers of intrinsic microporosity (PIMs) provide high surface area materials (typically 1000 m2 g-1 apparent BET surface area) that are processable from organic solvents to give glassy films or composite coatings. Multi-functionality for sensing with these materials is achieved (i) based on the polymer backbone itself being fluorescent or chemically active or (ii) based on guest species (chromophores, nano-catalysts, nano-photo-catalysts, etc.) that are readily embedded into PIMs and accessible through micropores in the polymer host. The ease of forming uniform microporous films or composite films is linked to molecular rigidity and highlighted here for sensing/electroanalytical applications.

Original language	English
Article number	100765
Journal	Current Opinion in Chemical Engineering
Volume	35
Early online date	30 Nov 2021
DOIs	https://doi.org/10.1016/j.coche.2021.100765
Publication status	Published - 31 Mar 2022

Bibliographical note

Funding Information:
L.W. thanks the China Scholarship Council ( 201906870022 ) for a PhD stipend. Y.Z. thanks the China Scholarship Council (CSC scholarship No 20180935006 ) for a PhD scholarship. F.M. thanks EPSRC for support ( EP/N013778/1 ).

ASJC Scopus subject areas

General Energy

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10.1016/j.coche.2021.100765

PIMS_Current_Opinion_1e_revision.PDFAccepted author manuscript, 1.1 MBLicence: CC BY-NC-ND

Cite this

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title = "Polymers of Intrinsic Microporosity (PIMs) in Sensing and in Electroanalysis",

abstract = "Polymers of intrinsic microporosity (PIMs) provide high surface area materials (typically 1000 m2 g-1 apparent BET surface area) that are processable from organic solvents to give glassy films or composite coatings. Multi-functionality for sensing with these materials is achieved (i) based on the polymer backbone itself being fluorescent or chemically active or (ii) based on guest species (chromophores, nano-catalysts, nano-photo-catalysts, etc.) that are readily embedded into PIMs and accessible through micropores in the polymer host. The ease of forming uniform microporous films or composite films is linked to molecular rigidity and highlighted here for sensing/electroanalytical applications. ",

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note = "Funding Information: L.W. thanks the China Scholarship Council ( 201906870022 ) for a PhD stipend. Y.Z. thanks the China Scholarship Council (CSC scholarship No 20180935006 ) for a PhD scholarship. F.M. thanks EPSRC for support ( EP/N013778/1 ). ",

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AU - Marken, Frank

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AU - Li, Zhongkai

AU - Amiri, Mandana

AU - Imanzadeh, Hamideh

N1 - Funding Information: L.W. thanks the China Scholarship Council ( 201906870022 ) for a PhD stipend. Y.Z. thanks the China Scholarship Council (CSC scholarship No 20180935006 ) for a PhD scholarship. F.M. thanks EPSRC for support ( EP/N013778/1 ).

PY - 2022/3/31

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N2 - Polymers of intrinsic microporosity (PIMs) provide high surface area materials (typically 1000 m2 g-1 apparent BET surface area) that are processable from organic solvents to give glassy films or composite coatings. Multi-functionality for sensing with these materials is achieved (i) based on the polymer backbone itself being fluorescent or chemically active or (ii) based on guest species (chromophores, nano-catalysts, nano-photo-catalysts, etc.) that are readily embedded into PIMs and accessible through micropores in the polymer host. The ease of forming uniform microporous films or composite films is linked to molecular rigidity and highlighted here for sensing/electroanalytical applications.

AB - Polymers of intrinsic microporosity (PIMs) provide high surface area materials (typically 1000 m2 g-1 apparent BET surface area) that are processable from organic solvents to give glassy films or composite coatings. Multi-functionality for sensing with these materials is achieved (i) based on the polymer backbone itself being fluorescent or chemically active or (ii) based on guest species (chromophores, nano-catalysts, nano-photo-catalysts, etc.) that are readily embedded into PIMs and accessible through micropores in the polymer host. The ease of forming uniform microporous films or composite films is linked to molecular rigidity and highlighted here for sensing/electroanalytical applications.

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Polymers of Intrinsic Microporosity (PIMs) in Sensing and in Electroanalysis

Abstract

Bibliographical note

ASJC Scopus subject areas

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