Polymers of Intrinsic Microporosity in the Design of Electrochemical Multi-Component and Multi-Phase Interfaces

Frank Marken; Mariolino Carta; Neil B. Mckeown

doi:10.1021/acs.analchem.0c04554

Polymers of Intrinsic Microporosity in the Design of Electrochemical Multi-Component and Multi-Phase Interfaces

Frank Marken, Mariolino Carta, Neil B. Mckeown

Research output: Contribution to journal › Review article › peer-review

22 Citations (SciVal)

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Abstract

Polymers of Intrinsic Microporosity (or PIMs) provide porous materials due to their highly contorted and rigid macromolecu-lar structures, which prevent space-efficient packing. PIMs are readily dissolved in solvents and can be cast into robust mi-croporous coatings and membranes. With a typical micropore size range of around 1 nm and a typical surface area of 700-1000 m2g-1, PIMs offer channels for ion/molecular transport and pores for gaseous species, solids, and liquids to coexist. Electrode surfaces are readily modified with coatings or composite films to provide interfaces for solid|solid|liquid or sol-id|liquid|liquid or solid|liquid|gas multiphase electrode processes.

Original language	English
Pages (from-to)	1213-1220
Number of pages	8
Journal	Analytical Chemistry
Volume	93
Issue number	3
Early online date	28 Dec 2020
DOIs	https://doi.org/10.1021/acs.analchem.0c04554
Publication status	Published - 26 Jan 2021

Bibliographical note

Funding Information:
The authors are grateful for support from the Leverhulme Foundation (Grant RPG2014-308: “New Materials for Ionic Diodes and Ionic Photodiodes”).

Funding

The authors are grateful for support from the Leverhulme Foundation (Grant RPG2014-308: “New Materials for Ionic Diodes and Ionic Photodiodes”).

ASJC Scopus subject areas

Analytical Chemistry

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10.1021/acs.analchem.0c04554

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This document is the Accepted Manuscript version of a Published Work that appeared in final form in Analytical Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.analchem.0c04554
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Cite this

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abstract = "Polymers of Intrinsic Microporosity (or PIMs) provide porous materials due to their highly contorted and rigid macromolecu-lar structures, which prevent space-efficient packing. PIMs are readily dissolved in solvents and can be cast into robust mi-croporous coatings and membranes. With a typical micropore size range of around 1 nm and a typical surface area of 700-1000 m2g-1, PIMs offer channels for ion/molecular transport and pores for gaseous species, solids, and liquids to coexist. Electrode surfaces are readily modified with coatings or composite films to provide interfaces for solid|solid|liquid or sol-id|liquid|liquid or solid|liquid|gas multiphase electrode processes. ",

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Polymers of Intrinsic Microporosity in the Design of Electrochemical Multi-Component and Multi-Phase Interfaces

Abstract

Bibliographical note

Funding

ASJC Scopus subject areas

Access to Document

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