Polymerisation resistant synthesis of methacrylamido phenylboronic acids

F D'Hooge; D Rogalle; Michael J Thatcher; Semali Perera; J M H van den Elsen; T A Jenkins; Tony James; John Fossey

doi:10.1016/j.polymer.2008.05.039

Polymerisation resistant synthesis of methacrylamido phenylboronic acids

F D'Hooge, D Rogalle, Michael J Thatcher, Semali Perera, J M H van den Elsen, T A Jenkins, Tony James, John Fossey

Research output: Contribution to journal › Article › peer-review

24 Citations (SciVal)

Abstract

Acrylamido boronic acids are important building blocks for functional polymers but suffer from poor synthetic strategies and unwanted polymerisation. A two-step deprotection of pinacolato methacrylamido phenylene boronic esters to generate 2-, 3- and 4-methacrylamido phenylboronic acids in good yield and purity is reported. Boronic acid containing methacrylamido monomers are now available in good yields for incorporation into polymers.

Original language	English
Pages (from-to)	3362-3365
Number of pages	4
Journal	Polymer
Volume	49
Issue number	16
DOIs	https://doi.org/10.1016/j.polymer.2008.05.039
Publication status	Published - 28 Jul 2008

Keywords

Acrylamide
Boronic acid
Deprotection

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10.1016/j.polymer.2008.05.039

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title = "Polymerisation resistant synthesis of methacrylamido phenylboronic acids",

abstract = "Acrylamido boronic acids are important building blocks for functional polymers but suffer from poor synthetic strategies and unwanted polymerisation. A two-step deprotection of pinacolato methacrylamido phenylene boronic esters to generate 2-, 3- and 4-methacrylamido phenylboronic acids in good yield and purity is reported. Boronic acid containing methacrylamido monomers are now available in good yields for incorporation into polymers.",

keywords = "Acrylamide, Boronic acid, Deprotection",

author = "F D'Hooge and D Rogalle and Thatcher, \{Michael J\} and Semali Perera and \{van den Elsen\}, \{J M H\} and Jenkins, \{T A\} and Tony James and John Fossey",

year = "2008",

month = jul,

day = "28",

doi = "10.1016/j.polymer.2008.05.039",

language = "English",

volume = "49",

pages = "3362--3365",

journal = "Polymer",

issn = "0032-3861",

publisher = "Elsevier B.V.",

number = "16",

}

TY - JOUR

T1 - Polymerisation resistant synthesis of methacrylamido phenylboronic acids

AU - D'Hooge, F

AU - Rogalle, D

AU - Thatcher, Michael J

AU - Perera, Semali

AU - van den Elsen, J M H

AU - Jenkins, T A

AU - James, Tony

AU - Fossey, John

PY - 2008/7/28

Y1 - 2008/7/28

N2 - Acrylamido boronic acids are important building blocks for functional polymers but suffer from poor synthetic strategies and unwanted polymerisation. A two-step deprotection of pinacolato methacrylamido phenylene boronic esters to generate 2-, 3- and 4-methacrylamido phenylboronic acids in good yield and purity is reported. Boronic acid containing methacrylamido monomers are now available in good yields for incorporation into polymers.

AB - Acrylamido boronic acids are important building blocks for functional polymers but suffer from poor synthetic strategies and unwanted polymerisation. A two-step deprotection of pinacolato methacrylamido phenylene boronic esters to generate 2-, 3- and 4-methacrylamido phenylboronic acids in good yield and purity is reported. Boronic acid containing methacrylamido monomers are now available in good yields for incorporation into polymers.

KW - Acrylamide

KW - Boronic acid

KW - Deprotection

UR - https://www.scopus.com/pages/publications/47149083992

UR - http://dx.doi.org/10.1016/j.polymer.2008.05.039

U2 - 10.1016/j.polymer.2008.05.039

DO - 10.1016/j.polymer.2008.05.039

M3 - Article

SN - 0032-3861

VL - 49

SP - 3362

EP - 3365

JO - Polymer

JF - Polymer

IS - 16

ER -

Polymerisation resistant synthesis of methacrylamido phenylboronic acids

Abstract

Keywords

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