Abstract
The reactivity of [{SiNDipp}AlK]2, which comprises a formally anionic Al(I) centre, has been examined towards a variety of 1,3-dienic molecules, including 2,3-dimethylbutadiene, cyclooctatetraene, anthracene and tetracene. In each case, the alumanyl derivative experiences oxidative addition across the Al(I) centre to provide the corresponding potassium aluminacyclopentene, aluminacyclopropene or aluminanorbornadiene products of [4 + 1] cycloaddition.
| Original language | English |
|---|---|
| Article number | e202400125 |
| Journal | Zeitschrift für Anorganische und Allgemeine Chemie |
| Volume | 650 |
| Issue number | 22 |
| Early online date | 10 Sept 2024 |
| DOIs | |
| Publication status | Published - 18 Nov 2024 |
Data Availability Statement
The data that support the findings of this study are available in the supplementary material of this article.Funding
Engineering and Physical Sciences Research Council - EP/R020752/1
| Funders | Funder number |
|---|---|
| Engineering and Physical Sciences Research Council |
Keywords
- alumanyl
- cycloaddition
- low oxidation states
- main group chemistry
ASJC Scopus subject areas
- Inorganic Chemistry
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Dive into the research topics of 'Polyene and Arene [4 + 1] Cycloaddition at a Seven-Membered Cyclic Alumanyl'. Together they form a unique fingerprint.Projects
- 1 Finished
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Nucleophilic alkaline earth boryls: from conception and theory to application
Hill, M. (PI), Cresswell, A. (CoI) & McMullin, C. (Researcher)
Engineering and Physical Sciences Research Council
1/05/18 → 31/07/22
Project: Research council
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