Polyene and Arene [4 + 1] Cycloaddition at a Seven-Membered Cyclic Alumanyl

Michael Hill; Han-Ying Liu; Mary Mahon

doi:10.1002/zaac.202400125

Polyene and Arene [4 + 1] Cycloaddition at a Seven-Membered Cyclic Alumanyl

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Abstract

The reactivity of [{SiNDipp}AlK]2, which comprises a formally anionic Al(I) centre, has been examined towards a variety of 1,3-dienic molecules, including 2,3-dimethylbutadiene, cyclooctatetraene, anthracene and tetracene. In each case, the alumanyl derivative experiences oxidative addition across the Al(I) centre to provide the corresponding potassium aluminacyclopentene, aluminacyclopropene or aluminanorbornadiene products of [4 + 1] cycloaddition.

Original language	English
Article number	e202400125
Journal	Zeitschrift für Anorganische und Allgemeine Chemie
DOIs	https://doi.org/10.1002/zaac.202400125
Publication status	Acceptance date - 21 Jul 2024

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10.1002/zaac.202400125

Nucleophilic alkaline earth boryls: from conception and theory to application
Hill, M. (PI), Cresswell, A. (CoI) & McMullin, C. (Researcher)
Engineering and Physical Sciences Research Council
1/05/18 → 31/07/22
Project: Research council

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title = "Polyene and Arene [4 + 1] Cycloaddition at a Seven-Membered Cyclic Alumanyl",

abstract = "The reactivity of [{SiNDipp}AlK]2, which comprises a formally anionic Al(I) centre, has been examined towards a variety of 1,3-dienic molecules, including 2,3-dimethylbutadiene, cyclooctatetraene, anthracene and tetracene. In each case, the alumanyl derivative experiences oxidative addition across the Al(I) centre to provide the corresponding potassium aluminacyclopentene, aluminacyclopropene or aluminanorbornadiene products of [4 + 1] cycloaddition.",

author = "Michael Hill and Han-Ying Liu and Mary Mahon",

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AU - Hill, Michael

AU - Liu, Han-Ying

AU - Mahon, Mary

PY - 2024/7/21

Y1 - 2024/7/21

N2 - The reactivity of [{SiNDipp}AlK]2, which comprises a formally anionic Al(I) centre, has been examined towards a variety of 1,3-dienic molecules, including 2,3-dimethylbutadiene, cyclooctatetraene, anthracene and tetracene. In each case, the alumanyl derivative experiences oxidative addition across the Al(I) centre to provide the corresponding potassium aluminacyclopentene, aluminacyclopropene or aluminanorbornadiene products of [4 + 1] cycloaddition.

AB - The reactivity of [{SiNDipp}AlK]2, which comprises a formally anionic Al(I) centre, has been examined towards a variety of 1,3-dienic molecules, including 2,3-dimethylbutadiene, cyclooctatetraene, anthracene and tetracene. In each case, the alumanyl derivative experiences oxidative addition across the Al(I) centre to provide the corresponding potassium aluminacyclopentene, aluminacyclopropene or aluminanorbornadiene products of [4 + 1] cycloaddition.

U2 - 10.1002/zaac.202400125

DO - 10.1002/zaac.202400125

M3 - Article

SN - 0044-2313

JO - Zeitschrift für Anorganische und Allgemeine Chemie

JF - Zeitschrift für Anorganische und Allgemeine Chemie

M1 - e202400125

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Polyene and Arene [4 + 1] Cycloaddition at a Seven-Membered Cyclic Alumanyl

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Nucleophilic alkaline earth boryls: from conception and theory to application

Cite this