Platinum-catalyzed synthesis of trichloroamidines.

Jay J. Dunsford; Jason E. Camp

doi:10.1016/j.tetlet.2013.06.062

Platinum-catalyzed synthesis of trichloroamidines.

Jay J. Dunsford, Jason E. Camp

Department of Chemistry

University of Nottingham

Research output: Contribution to journal › Article › peer-review

6 Citations (SciVal)

Abstract

A mild platinum-catalyzed method for the formation of free amidines from the reaction of amines and trichloroacetonitrile in nonpolar solvents has been developed. This protocol provides access to novel amidines that in some cases (4b-d) cannot be synthesized via the direct reaction of amines and halogenated nitriles. [on SciFinder(R)]

Original language	English
Pages (from-to)	4522-4523
Number of pages	2
Journal	Tetrahedron Letters
Volume	54
Issue number	34
Early online date	22 Jun 2013
DOIs	https://doi.org/10.1016/j.tetlet.2013.06.062
Publication status	Published - 21 Aug 2013

Bibliographical note

M1 - Copyright (C) 2018 American Chemical Society (ACS). All Rights Reserved.

CAPLUS AN 2013:1096259(Journal; Online Computer File)

Keywords

trichloroamidine prepn amine trichloroacetonitrile platinum catalyst

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10.1016/j.tetlet.2013.06.062

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abstract = "A mild platinum-catalyzed method for the formation of free amidines from the reaction of amines and trichloroacetonitrile in nonpolar solvents has been developed. This protocol provides access to novel amidines that in some cases (4b-d) cannot be synthesized via the direct reaction of amines and halogenated nitriles. [on SciFinder(R)]",

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AU - Camp, Jason E.

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N2 - A mild platinum-catalyzed method for the formation of free amidines from the reaction of amines and trichloroacetonitrile in nonpolar solvents has been developed. This protocol provides access to novel amidines that in some cases (4b-d) cannot be synthesized via the direct reaction of amines and halogenated nitriles. [on SciFinder(R)]

AB - A mild platinum-catalyzed method for the formation of free amidines from the reaction of amines and trichloroacetonitrile in nonpolar solvents has been developed. This protocol provides access to novel amidines that in some cases (4b-d) cannot be synthesized via the direct reaction of amines and halogenated nitriles. [on SciFinder(R)]

KW - trichloroamidine prepn amine trichloroacetonitrile platinum catalyst

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DO - 10.1016/j.tetlet.2013.06.062

M3 - Article

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EP - 4523

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 34

ER -

Platinum-catalyzed synthesis of trichloroamidines.

Abstract

Bibliographical note

Keywords

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