Platinum-catalyzed synthesis of trichloroamidines.

Jay J. Dunsford, Jason E. Camp

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

A mild platinum-catalyzed method for the formation of free amidines from the reaction of amines and trichloroacetonitrile in nonpolar solvents has been developed. This protocol provides access to novel amidines that in some cases (4b-d) cannot be synthesized via the direct reaction of amines and halogenated nitriles. [on SciFinder(R)]
Original languageEnglish
Pages (from-to)4522-4523
Number of pages2
JournalTetrahedron Letters
Volume54
Issue number34
Early online date22 Jun 2013
DOIs
Publication statusPublished - 21 Aug 2013

Keywords

  • trichloroamidine prepn amine trichloroacetonitrile platinum catalyst

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