Photoelectroanalytical Oxygen Detection with Titanate Nanosheet - Platinum Hybrids Immobilised into a Polymer of Intrinsic Microporosity (PIM-1)

Frank Marken, Yuanzhu Zhao, Budi Riza Putra Putra, Bingbing Fan, Christian Harito, Dmitry V Bavykin, Frank C Walsh, Mariolino Carta, R. Malpass-Evans, Neil B. Mckeown

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

The polymer of intrinsic microporosity PIM-1 is employed to disperse and deposit a Pt@titanate nanosheet photocatalyst film. The resulting microporous films allow electrolyte and oxygen permeation to give conventional oxygen reduction voltammetric responses on glassy carbon or on platinum disk electrodes in the dark. Preliminary data are presented showing that with pulsed light from a blue LED (385 nm) oxygen reduction at the electrode is effectively “switched off”. A mechanism is tentatively assigned as photocatalytic depletion of oxygen near the electrode. Photoelectrochemical current responses are observed in aqueous NaOH, NaCl, Na2HPO4 and shown to be light intensity and oxygen concentration dependent. Electroanalytical applications are suggested.
Original languageEnglish
Pages (from-to)2756-2763
JournalElectroanalysis
Volume32
Issue number12
Early online date3 Sep 2020
DOIs
Publication statusPublished - 31 Dec 2020

Fingerprint Dive into the research topics of 'Photoelectroanalytical Oxygen Detection with Titanate Nanosheet - Platinum Hybrids Immobilised into a Polymer of Intrinsic Microporosity (PIM-1)'. Together they form a unique fingerprint.

Cite this