Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)(4)(H2O)(eta(1)-OSO)][MeC6H4SO3](2)

K F Bowes; J M Cole; S L G Husheer; P R Raithby; T L Savarese; H A Sparkes; S J Teat; J E Warren

doi:10.1039/b604039

Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)(4)(H2O)(eta(1)-OSO)][MeC6H4SO3](2)

K F Bowes, J M Cole, S L G Husheer, P R Raithby, T L Savarese, H A Sparkes, S J Teat, J E Warren

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The structure of a new metastable geometric isomer of [Ru(NH3)(4)(H2O)(SO2)][MeC6H4SO3](2) in which the SO2 group is coordinated through a single oxygen in an eta(1)-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36% component of the structure within a single crystal upon irradiation using a tungsten lamp.

Original language	English
Pages (from-to)	2448-2450
Number of pages	3
Journal	Chemical Communications
Issue number	23
DOIs	https://doi.org/10.1039/b604039
Publication status	Published - 2006

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ID number: ISI:000238101100005

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10.1039/b604039

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title = "Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)(4)(H2O)(eta(1)-OSO)][MeC6H4SO3](2)",

abstract = "The structure of a new metastable geometric isomer of [Ru(NH3)(4)(H2O)(SO2)][MeC6H4SO3](2) in which the SO2 group is coordinated through a single oxygen in an eta(1)-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36\% component of the structure within a single crystal upon irradiation using a tungsten lamp.",

author = "Bowes, \{K F\} and Cole, \{J M\} and Husheer, \{S L G\} and Raithby, \{P R\} and Savarese, \{T L\} and Sparkes, \{H A\} and Teat, \{S J\} and Warren, \{J E\}",

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year = "2006",

doi = "10.1039/b604039",

language = "English",

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journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)(4)(H2O)(eta(1)-OSO)][MeC6H4SO3](2)

AU - Bowes, K F

AU - Cole, J M

AU - Husheer, S L G

AU - Raithby, P R

AU - Savarese, T L

AU - Sparkes, H A

AU - Teat, S J

AU - Warren, J E

N1 - ID number: ISI:000238101100005

PY - 2006

Y1 - 2006

N2 - The structure of a new metastable geometric isomer of [Ru(NH3)(4)(H2O)(SO2)][MeC6H4SO3](2) in which the SO2 group is coordinated through a single oxygen in an eta(1)-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36% component of the structure within a single crystal upon irradiation using a tungsten lamp.

AB - The structure of a new metastable geometric isomer of [Ru(NH3)(4)(H2O)(SO2)][MeC6H4SO3](2) in which the SO2 group is coordinated through a single oxygen in an eta(1)-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36% component of the structure within a single crystal upon irradiation using a tungsten lamp.

U2 - 10.1039/b604039

DO - 10.1039/b604039

M3 - Article

SN - 1359-7345

SP - 2448

EP - 2450

JO - Chemical Communications

JF - Chemical Communications

IS - 23

ER -

Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)(4)(H2O)(eta(1)-OSO)][MeC6H4SO3](2)

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