Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)4(H2O)(η1-OSO)][MeC 6H4SO3]2

Katharine F. Bowes, Jacqueline M. Cole, Shamus L.G. Husheer, Paul R. Raithby, Teresa L. Savarese, Hazel A. Sparkes, Simon J. Teat, John E. Warren

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63 Citations (Scopus)

Abstract

The structure of a new metastable geometric isomer of [Ru(NH 3)4(H2O)(SO2)][MeC6H 4SO3]2 in which the SO2 group is coordinated through a single oxygen in an η1-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36% component of the structure within a single crystal upon irradiation using a tungsten lamp.

Original languageEnglish
Pages (from-to)2448-2450
Number of pages3
JournalChemical Communications
Issue number23
DOIs
Publication statusPublished - 2006

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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