Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)4(H2O)(η1-OSO)][MeC 6H4SO3]2

Katharine F. Bowes; Jacqueline M. Cole; Shamus L.G. Husheer; Paul R. Raithby; Teresa L. Savarese; Hazel A. Sparkes; Simon J. Teat; John E. Warren

doi:10.1039/b604039j

Photocrystallographic structure determination of a new geometric isomer of [Ru(NH₃)₄(H₂O)(η¹-OSO)][MeC ₆H₄SO₃]₂

Katharine F. Bowes, Jacqueline M. Cole, Shamus L.G. Husheer, Paul R. Raithby, Teresa L. Savarese, Hazel A. Sparkes, Simon J. Teat, John E. Warren

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

76 Citations (SciVal)

Abstract

The structure of a new metastable geometric isomer of [Ru(NH ₃)₄(H₂O)(SO₂)][MeC₆H ₄SO₃]₂ in which the SO₂ group is coordinated through a single oxygen in an η¹-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36% component of the structure within a single crystal upon irradiation using a tungsten lamp.

Original language	English
Pages (from-to)	2448-2450
Number of pages	3
Journal	Chemical Communications
Issue number	23
DOIs	https://doi.org/10.1039/b604039j
Publication status	Published - 2006

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/b604039j

Cite this

@article{cf1633851b644c0c8fa68a7bd91c9bd9,

title = "Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)4(H2O)(η1-OSO)][MeC 6H4SO3]2",

abstract = "The structure of a new metastable geometric isomer of [Ru(NH 3)4(H2O)(SO2)][MeC6H 4SO3]2 in which the SO2 group is coordinated through a single oxygen in an η1-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36% component of the structure within a single crystal upon irradiation using a tungsten lamp.",

author = "Bowes, {Katharine F.} and Cole, {Jacqueline M.} and Husheer, {Shamus L.G.} and Raithby, {Paul R.} and Savarese, {Teresa L.} and Sparkes, {Hazel A.} and Teat, {Simon J.} and Warren, {John E.}",

year = "2006",

doi = "10.1039/b604039j",

language = "English",

pages = "2448--2450",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "23",

}

TY - JOUR

T1 - Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)4(H2O)(η1-OSO)][MeC 6H4SO3]2

AU - Bowes, Katharine F.

AU - Cole, Jacqueline M.

AU - Husheer, Shamus L.G.

AU - Raithby, Paul R.

AU - Savarese, Teresa L.

AU - Sparkes, Hazel A.

AU - Teat, Simon J.

AU - Warren, John E.

PY - 2006

Y1 - 2006

N2 - The structure of a new metastable geometric isomer of [Ru(NH 3)4(H2O)(SO2)][MeC6H 4SO3]2 in which the SO2 group is coordinated through a single oxygen in an η1-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36% component of the structure within a single crystal upon irradiation using a tungsten lamp.

AB - The structure of a new metastable geometric isomer of [Ru(NH 3)4(H2O)(SO2)][MeC6H 4SO3]2 in which the SO2 group is coordinated through a single oxygen in an η1-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36% component of the structure within a single crystal upon irradiation using a tungsten lamp.

UR - http://www.scopus.com/inward/record.url?scp=33745052144&partnerID=8YFLogxK

U2 - 10.1039/b604039j

DO - 10.1039/b604039j

M3 - Article

AN - SCOPUS:33745052144

SN - 1359-7345

SP - 2448

EP - 2450

JO - Chemical Communications

JF - Chemical Communications

IS - 23

ER -

Photocrystallographic structure determination of a new geometric isomer of [Ru(NH₃)₄(H₂O)(η¹-OSO)][MeC ₆H₄SO₃]₂

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this