Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)(4)(H2O)(eta(1)-OSO)][MeC6H4SO3](2)

K F Bowes; J M Cole; S L G Husheer; P R Raithby; T L Savarese; H A Sparkes; S J Teat; J E Warren

doi:10.1039/b604039

Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)(4)(H2O)(eta(1)-OSO)][MeC6H4SO3](2)

K F Bowes, J M Cole, S L G Husheer, P R Raithby, T L Savarese, H A Sparkes, S J Teat, J E Warren

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The structure of a new metastable geometric isomer of [Ru(NH3)(4)(H2O)(SO2)][MeC6H4SO3](2) in which the SO2 group is coordinated through a single oxygen in an eta(1)-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36% component of the structure within a single crystal upon irradiation using a tungsten lamp.

Original language	English
Pages (from-to)	2448-2450
Number of pages	3
Journal	Chemical Communications
Issue number	23
DOIs	https://doi.org/10.1039/b604039
Publication status	Published - 2006

Access to Document

10.1039/b604039

Cite this

@article{43d21b79ac8246c4a0bb58ac921554cc,

title = "Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)(4)(H2O)(eta(1)-OSO)][MeC6H4SO3](2)",

abstract = "The structure of a new metastable geometric isomer of [Ru(NH3)(4)(H2O)(SO2)][MeC6H4SO3](2) in which the SO2 group is coordinated through a single oxygen in an eta(1)-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36% component of the structure within a single crystal upon irradiation using a tungsten lamp.",

author = "Bowes, {K F} and Cole, {J M} and Husheer, {S L G} and Raithby, {P R} and Savarese, {T L} and Sparkes, {H A} and Teat, {S J} and Warren, {J E}",

note = "ID number: ISI:000238101100005",

year = "2006",

doi = "10.1039/b604039",

language = "English",

pages = "2448--2450",

journal = "Chemical communications (Cambridge, England)",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "23",

}

TY - JOUR

T1 - Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)(4)(H2O)(eta(1)-OSO)][MeC6H4SO3](2)

AU - Bowes, K F

AU - Cole, J M

AU - Husheer, S L G

AU - Raithby, P R

AU - Savarese, T L

AU - Sparkes, H A

AU - Teat, S J

AU - Warren, J E

N1 - ID number: ISI:000238101100005

PY - 2006

Y1 - 2006

N2 - The structure of a new metastable geometric isomer of [Ru(NH3)(4)(H2O)(SO2)][MeC6H4SO3](2) in which the SO2 group is coordinated through a single oxygen in an eta(1)-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36% component of the structure within a single crystal upon irradiation using a tungsten lamp.

AB - The structure of a new metastable geometric isomer of [Ru(NH3)(4)(H2O)(SO2)][MeC6H4SO3](2) in which the SO2 group is coordinated through a single oxygen in an eta(1)-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36% component of the structure within a single crystal upon irradiation using a tungsten lamp.

U2 - 10.1039/b604039

DO - 10.1039/b604039

M3 - Article

SP - 2448

EP - 2450

JO - Chemical communications (Cambridge, England)

JF - Chemical communications (Cambridge, England)

SN - 1359-7345

IS - 23

ER -

Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)(4)(H2O)(eta(1)-OSO)][MeC6H4SO3](2)

Abstract

Access to Document

Fingerprint

Cite this