Abstract
Organophosphorus compounds (OPCs) are highly important chemicals, finding numerous applications in both academia and industry. Herein we describe a simple photocatalytic method for the stannylation of white phosphorus (P4) using a cheap, commercially-available distannane, (Bu3Sn)2, and anthraquinone as a simple photocatalyst. Subsequent ‘one pot’ transformation of the resulting stannylated monophosphine intermediate (Bu3Sn)3P provides direct, convenient and versatile access to valuable OPCs such as acylated phosphines and tetraalkylphosphonium salts.
Original language | English |
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Pages (from-to) | 8986-8989 |
Journal | Chemical Communications |
Volume | 58 |
Early online date | 14 Jul 2022 |
DOIs | |
Publication status | Published - 23 Jul 2022 |