Photocatalytic stannylation of white phosphorus

Marion Till; Jose Cammarata; Robert Wolf; Daniel Scott

doi:10.1039/D2CC03474C

Photocatalytic stannylation of white phosphorus

Marion Till, Jose Cammarata, Robert Wolf, Daniel Scott

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

20 Citations (SciVal)

Abstract

Organophosphorus compounds (OPCs) are highly important chemicals, finding numerous applications in both academia and industry. Herein we describe a simple photocatalytic method for the stannylation of white phosphorus (P₄) using a cheap, commercially-available distannane, (Bu₃Sn)₂, and anthraquinone as a simple photocatalyst. Subsequent ‘one pot’ transformation of the resulting stannylated monophosphine intermediate (Bu₃Sn)₃P provides direct, convenient and versatile access to valuable OPCs such as acylated phosphines and tetraalkylphosphonium salts.

Original language	English
Pages (from-to)	8986-8989
Journal	Chemical Communications
Volume	58
Early online date	14 Jul 2022
DOIs	https://doi.org/10.1039/D2CC03474C
Publication status	Published - 23 Jul 2022

Access to Document

10.1039/D2CC03474CLicence: CC BY

Cite this

@article{052f8ba24233486fb31316cd7655ec80,

title = "Photocatalytic stannylation of white phosphorus",

abstract = "Organophosphorus compounds (OPCs) are highly important chemicals, finding numerous applications in both academia and industry. Herein we describe a simple photocatalytic method for the stannylation of white phosphorus (P4) using a cheap, commercially-available distannane, (Bu3Sn)2, and anthraquinone as a simple photocatalyst. Subsequent {\textquoteleft}one pot{\textquoteright} transformation of the resulting stannylated monophosphine intermediate (Bu3Sn)3P provides direct, convenient and versatile access to valuable OPCs such as acylated phosphines and tetraalkylphosphonium salts.",

author = "Marion Till and Jose Cammarata and Robert Wolf and Daniel Scott",

year = "2022",

month = jul,

day = "23",

doi = "10.1039/D2CC03474C",

language = "English",

volume = "58",

pages = "8986--8989",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

}

TY - JOUR

T1 - Photocatalytic stannylation of white phosphorus

AU - Till, Marion

AU - Cammarata, Jose

AU - Wolf, Robert

AU - Scott, Daniel

PY - 2022/7/23

Y1 - 2022/7/23

N2 - Organophosphorus compounds (OPCs) are highly important chemicals, finding numerous applications in both academia and industry. Herein we describe a simple photocatalytic method for the stannylation of white phosphorus (P4) using a cheap, commercially-available distannane, (Bu3Sn)2, and anthraquinone as a simple photocatalyst. Subsequent ‘one pot’ transformation of the resulting stannylated monophosphine intermediate (Bu3Sn)3P provides direct, convenient and versatile access to valuable OPCs such as acylated phosphines and tetraalkylphosphonium salts.

AB - Organophosphorus compounds (OPCs) are highly important chemicals, finding numerous applications in both academia and industry. Herein we describe a simple photocatalytic method for the stannylation of white phosphorus (P4) using a cheap, commercially-available distannane, (Bu3Sn)2, and anthraquinone as a simple photocatalyst. Subsequent ‘one pot’ transformation of the resulting stannylated monophosphine intermediate (Bu3Sn)3P provides direct, convenient and versatile access to valuable OPCs such as acylated phosphines and tetraalkylphosphonium salts.

U2 - 10.1039/D2CC03474C

DO - 10.1039/D2CC03474C

M3 - Article

SN - 1359-7345

VL - 58

SP - 8986

EP - 8989

JO - Chemical Communications

JF - Chemical Communications

ER -

Photocatalytic stannylation of white phosphorus

Abstract

Access to Document

Fingerprint

Cite this