Phosphorus-substituted azulenes accessed via direct hafner reaction of a phosphino cyclopentadienide

Anthony Gee; Samuel D. Cosham; Andrew L. Johnson; Simon E. Lewis

doi:10.1055/s-0036-1589936

Phosphorus-substituted azulenes accessed via direct hafner reaction of a phosphino cyclopentadienide

Anthony Gee, Samuel D. Cosham, Andrew L. Johnson, Simon E. Lewis

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Abstract

The Hafner azulene synthesis may be applied to the direct synthesis of phosphorus-substituted azulenes, when a phosphinocyclopentadienide is used as one of the reactants. The azulenyl phosphines produced in this fashion are preferentially isolated as the corresponding phosphine oxides or phosphine borane adducts.

Original language	English
Pages (from-to)	973-975
Number of pages	3
Journal	Synlett
Volume	2017
Issue number	28
Early online date	17 Jan 2017
DOIs	https://doi.org/10.1055/s-0036-1589936
Publication status	Published - 14 Feb 2017

Keywords

azulene
cyclopentadienide
phosphine
pyrylium salt
borane adduct

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-0036-1589936

LewisSynlettAccepted author manuscript, 925 KB

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abstract = "The Hafner azulene synthesis may be applied to the direct synthesis of phosphorus-substituted azulenes, when a phosphinocyclopentadienide is used as one of the reactants. The azulenyl phosphines produced in this fashion are preferentially isolated as the corresponding phosphine oxides or phosphine borane adducts.",

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AU - Gee, Anthony

AU - Cosham, Samuel D.

AU - Johnson, Andrew L.

AU - Lewis, Simon E.

PY - 2017/2/14

Y1 - 2017/2/14

N2 - The Hafner azulene synthesis may be applied to the direct synthesis of phosphorus-substituted azulenes, when a phosphinocyclopentadienide is used as one of the reactants. The azulenyl phosphines produced in this fashion are preferentially isolated as the corresponding phosphine oxides or phosphine borane adducts.

AB - The Hafner azulene synthesis may be applied to the direct synthesis of phosphorus-substituted azulenes, when a phosphinocyclopentadienide is used as one of the reactants. The azulenyl phosphines produced in this fashion are preferentially isolated as the corresponding phosphine oxides or phosphine borane adducts.

KW - azulene

KW - cyclopentadienide

KW - phosphine

KW - pyrylium salt

KW - borane adduct

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ER -

Phosphorus-substituted azulenes accessed via direct hafner reaction of a phosphino cyclopentadienide

Abstract

Keywords

ASJC Scopus subject areas

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