Phosphorus-substituted azulenes accessed via direct hafner reaction of a phosphino cyclopentadienide

Anthony Gee, Samuel D. Cosham, Andrew L. Johnson, Simon E. Lewis

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The Hafner azulene synthesis may be applied to the direct synthesis of phosphorus-substituted azulenes, when a phosphinocyclopentadienide is used as one of the reactants. The azulenyl phosphines produced in this fashion are preferentially isolated as the corresponding phosphine oxides or phosphine borane adducts.

LanguageEnglish
Pages973-975
Number of pages3
JournalSynlett
Volume2017
Issue number28
Early online date17 Jan 2017
DOIs
StatusPublished - 14 Feb 2017

Fingerprint

phosphine
Azulenes
Phosphorus
Phosphines
Boranes
Oxides

Keywords

  • azulene
  • cyclopentadienide
  • phosphine
  • pyrylium salt
  • ­borane adduct

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Phosphorus-substituted azulenes accessed via direct hafner reaction of a phosphino cyclopentadienide. / Gee, Anthony; Cosham, Samuel D.; Johnson, Andrew L.; Lewis, Simon E.

In: Synlett, Vol. 2017, No. 28, 14.02.2017, p. 973-975.

Research output: Contribution to journalArticle

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