Abstract
The one-pot aminolysis/thiol-ene chain-end modification between a well-defined trithiocarbonate-functionalized poly(N-isopropylacrylamide) (DP n = 13 and PDI = 1.06) and N-phenyl maleimide has been investigated using triethylphosphite (P(OEt) 3) as a coreagent. A quantitative chain-end functionalization has been obtained as shown by 1H NMR spectroscopy and MALDI-TOF mass spectrometry.
Original language | English |
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Pages (from-to) | 1657-1661 |
Number of pages | 5 |
Journal | Journal of Polymer Science, Part A: Polymer Chemistry |
Volume | 50 |
Issue number | 8 |
DOIs | |
Publication status | Published - 15 Apr 2012 |
Keywords
- "click"chemistry
- functionalization of polymers
- radical polymerization
- reversible addition fragmentation chain transfer (RAFT)
- synthesis
ASJC Scopus subject areas
- Materials Chemistry
- Polymers and Plastics
- Organic Chemistry