Phosphine-olefin ligands: A facile dehydrogenative route to catalytically active rhodium complexes

T.M. Douglas, Jerome Le Notre, S.K. Brayshaw, C.G. Frost, A.S. Weller

Research output: Contribution to journalArticle

42 Citations (Scopus)

Abstract

Facile, metal-mediated, (acceptorless) dehydrogenation of tricyclopentyl phosphine directly affords rhodium chelating phosphine-olefin complexes, some of which are catalytically active for 1,4-additions.
Original languageEnglish
Pages (from-to)3408-3410
Number of pages3
JournalChemical Communications
Volume2006
Issue number32
Early online date20 Jun 2006
DOIs
Publication statusPublished - 2006

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