Phosphine-olefin ligands: A facile dehydrogenative route to catalytically active rhodium complexes

T.M. Douglas; Jerome Le Notre; S.K. Brayshaw; C.G. Frost; A.S. Weller

doi:10.1039/b608129k

Phosphine-olefin ligands: A facile dehydrogenative route to catalytically active rhodium complexes

T.M. Douglas, Jerome Le Notre, S.K. Brayshaw, C.G. Frost, A.S. Weller

Research output: Contribution to journal › Article › peer-review

45 Citations (SciVal)

Abstract

Facile, metal-mediated, (acceptorless) dehydrogenation of tricyclopentyl phosphine directly affords rhodium chelating phosphine-olefin complexes, some of which are catalytically active for 1,4-additions.

Original language	English
Pages (from-to)	3408-3410
Number of pages	3
Journal	Chemical Communications
Volume	2006
Issue number	32
Early online date	20 Jun 2006
DOIs	https://doi.org/10.1039/b608129k
Publication status	Published - 2006

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@article{817caffef50443b3b0ca81d256cf03cd,

title = "Phosphine-olefin ligands: A facile dehydrogenative route to catalytically active rhodium complexes",

abstract = "Facile, metal-mediated, (acceptorless) dehydrogenation of tricyclopentyl phosphine directly affords rhodium chelating phosphine-olefin complexes, some of which are catalytically active for 1,4-additions. ",

author = "T.M. Douglas and {Le Notre}, Jerome and S.K. Brayshaw and C.G. Frost and A.S. Weller",

year = "2006",

doi = "10.1039/b608129k",

language = "English",

volume = "2006",

pages = "3408--3410",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Phosphine-olefin ligands

T2 - A facile dehydrogenative route to catalytically active rhodium complexes

AU - Douglas, T.M.

AU - Le Notre, Jerome

AU - Brayshaw, S.K.

AU - Frost, C.G.

AU - Weller, A.S.

PY - 2006

Y1 - 2006

N2 - Facile, metal-mediated, (acceptorless) dehydrogenation of tricyclopentyl phosphine directly affords rhodium chelating phosphine-olefin complexes, some of which are catalytically active for 1,4-additions.

AB - Facile, metal-mediated, (acceptorless) dehydrogenation of tricyclopentyl phosphine directly affords rhodium chelating phosphine-olefin complexes, some of which are catalytically active for 1,4-additions.

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UR - http://dx.doi.org/10.1039/b608129k

U2 - 10.1039/b608129k

DO - 10.1039/b608129k

M3 - Article

AN - SCOPUS:33746905144

SN - 1359-7345

VL - 2006

SP - 3408

EP - 3410

JO - Chemical Communications

JF - Chemical Communications

IS - 32

ER -

Phosphine-olefin ligands: A facile dehydrogenative route to catalytically active rhodium complexes

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