Phosphine-olefin ligands

A facile dehydrogenative route to catalytically active rhodium complexes

T.M. Douglas, Jerome Le Notre, S.K. Brayshaw, C.G. Frost, A.S. Weller

Research output: Contribution to journalArticle

41 Citations (Scopus)

Abstract

Facile, metal-mediated, (acceptorless) dehydrogenation of tricyclopentyl phosphine directly affords rhodium chelating phosphine-olefin complexes, some of which are catalytically active for 1,4-additions.
Original languageEnglish
Pages (from-to)3408-3410
Number of pages3
JournalChemical Communications
Volume2006
Issue number32
Early online date20 Jun 2006
DOIs
Publication statusPublished - 2006

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phosphine
Rhodium
Alkenes
Dehydrogenation
Chelation
Olefins
Ligands
Metals

Cite this

Phosphine-olefin ligands : A facile dehydrogenative route to catalytically active rhodium complexes. / Douglas, T.M.; Le Notre, Jerome; Brayshaw, S.K.; Frost, C.G.; Weller, A.S.

In: Chemical Communications, Vol. 2006, No. 32, 2006, p. 3408-3410.

Research output: Contribution to journalArticle

Douglas, T.M. ; Le Notre, Jerome ; Brayshaw, S.K. ; Frost, C.G. ; Weller, A.S. / Phosphine-olefin ligands : A facile dehydrogenative route to catalytically active rhodium complexes. In: Chemical Communications. 2006 ; Vol. 2006, No. 32. pp. 3408-3410.
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