Phosphine- and Amine-Borane Dehydrocoupling Using a Three Coordinate Iron(II) β-Diketiminate Pre-Catalyst

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• Finished

  EC Fellowship - Cast Iron Catalysis: New Protocols for the Synthesis of Carbon-Phosphorus Bonds

  Webster, R. (PI)

  Engineering and Physical Sciences Research Council

  3/12/17 → 2/03/24

  Project: Research council

  • formation 100%
  • pre-catalyst 87%
  • Alkyne 75%
  • Borane 75%
  • Ambient Reaction Temperature 74%

• A New Iron Age: Atom Efficient P-C Bond Forming Reactions with Simple, Designed Iron Catalysts

  Webster, R. (PI)

  Engineering and Physical Sciences Research Council

  20/04/15 → 19/04/16

  Project: Research council

  • pre-catalyst 100%
  • Alkene 66%
  • Cyclotrimerization 50%
  • Ambient Reaction Temperature 50%
  • Phosphorus 50%