Palladium-catalyzed isomerization of exo-methylenic allylic alcohols

Paul S Fordred; Dushmanthi G Niyadurupola; Richard Wisedale; Steven D Bull

doi:10.1002/adsc.200900309

Palladium-catalyzed isomerization of exo-methylenic allylic alcohols

Paul S Fordred
, Dushmanthi G Niyadurupola
, Richard Wisedale
, Steven D Bull

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (SciVal)

Abstract

Treatment of allylic alcohols containing a 1,1-disubstituted alkene with a palladium catalyst and hydrogen gas (1 bar) results in facile isomerization to their corresponding trisubstituted (E)-allylic alcohols, along with small amounts of the corresponding hydrogenated products.

Original language	English
Pages (from-to)	2310-2314
Number of pages	5
Journal	Advanced Synthesis & Catalysis
Volume	351
Issue number	14-15
DOIs	https://doi.org/10.1002/adsc.200900309
Publication status	Published - Oct 2009

Access to Document

10.1002/adsc.200900309

Cite this

@article{a803c7bfe665432c9b96bb868a184417,

title = "Palladium-catalyzed isomerization of exo-methylenic allylic alcohols",

abstract = "Treatment of allylic alcohols containing a 1,1-disubstituted alkene with a palladium catalyst and hydrogen gas (1 bar) results in facile isomerization to their corresponding trisubstituted (E)-allylic alcohols, along with small amounts of the corresponding hydrogenated products.",

author = "Fordred, \{Paul S\} and Niyadurupola, \{Dushmanthi G\} and Richard Wisedale and Bull, \{Steven D\}",

year = "2009",

month = oct,

doi = "10.1002/adsc.200900309",

language = "English",

volume = "351",

pages = "2310--2314",

journal = "Advanced Synthesis \& Catalysis",

publisher = "Wiley-VCH Verlag",

number = "14-15",

}

TY - JOUR

T1 - Palladium-catalyzed isomerization of exo-methylenic allylic alcohols

AU - Fordred, Paul S

AU - Niyadurupola, Dushmanthi G

AU - Wisedale, Richard

AU - Bull, Steven D

PY - 2009/10

Y1 - 2009/10

N2 - Treatment of allylic alcohols containing a 1,1-disubstituted alkene with a palladium catalyst and hydrogen gas (1 bar) results in facile isomerization to their corresponding trisubstituted (E)-allylic alcohols, along with small amounts of the corresponding hydrogenated products.

AB - Treatment of allylic alcohols containing a 1,1-disubstituted alkene with a palladium catalyst and hydrogen gas (1 bar) results in facile isomerization to their corresponding trisubstituted (E)-allylic alcohols, along with small amounts of the corresponding hydrogenated products.

UR - https://www.scopus.com/pages/publications/70350610678

UR - http://dx.doi.org/10.1002/adsc.200900309

U2 - 10.1002/adsc.200900309

DO - 10.1002/adsc.200900309

M3 - Article

VL - 351

SP - 2310

EP - 2314

JO - Advanced Synthesis & Catalysis

JF - Advanced Synthesis & Catalysis

IS - 14-15

ER -

Palladium-catalyzed isomerization of exo-methylenic allylic alcohols

Abstract

Access to Document

Other files and links

Fingerprint

Cite this