Palladium-catalyzed isomerization of exo-methylenic allylic alcohols

Paul S Fordred, Dushmanthi G Niyadurupola, Richard Wisedale, Steven D Bull

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Treatment of allylic alcohols containing a 1,1-disubstituted alkene with a palladium catalyst and hydrogen gas (1 bar) results in facile isomerization to their corresponding trisubstituted (E)-allylic alcohols, along with small amounts of the corresponding hydrogenated products.
Original languageEnglish
Pages (from-to)2310-2314
Number of pages5
JournalAdvanced Synthesis & Catalysis
Volume351
Issue number14-15
DOIs
Publication statusPublished - Oct 2009

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