Palladium-catalyzed isomerization of exo-methylenic allylic alcohols

Paul S Fordred, Dushmanthi G Niyadurupola, Richard Wisedale, Steven D Bull

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3 Citations (SciVal)


Treatment of allylic alcohols containing a 1,1-disubstituted alkene with a palladium catalyst and hydrogen gas (1 bar) results in facile isomerization to their corresponding trisubstituted (E)-allylic alcohols, along with small amounts of the corresponding hydrogenated products.
Original languageEnglish
Pages (from-to)2310-2314
Number of pages5
JournalAdvanced Synthesis & Catalysis
Issue number14-15
Publication statusPublished - Oct 2009


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