Palladium-catalysed ortho-arylation of carbamate-protected phenols

Robin B. Bedford; Ruth L. Webster; Charlotte J. Mitchell

doi:10.1039/b916724m

Palladium-catalysed ortho-arylation of carbamate-protected phenols

Robin B. Bedford, Ruth L. Webster, Charlotte J. Mitchell

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

75 Citations (SciVal)

Abstract

The carbamate (–O2CNR2) function is an excellent directing group for palladium-catalysed direct arylation reactions giving both protected or free mono- or di-substituted phenols, as well as an example of a dibenzopyranone, depending on coupling partners (aryl iodides or diaryliodonium salts) and conditions.

Original language	English
Pages (from-to)	4853-4857
Journal	Organic and Biomolecular Chemistry
Volume	7
Issue number	23
Early online date	29 Sept 2009
DOIs	https://doi.org/10.1039/b916724m
Publication status	Published - 2009

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title = "Palladium-catalysed ortho-arylation of carbamate-protected phenols",

abstract = "The carbamate (–O2CNR2) function is an excellent directing group for palladium-catalysed direct arylation reactions giving both protected or free mono- or di-substituted phenols, as well as an example of a dibenzopyranone, depending on coupling partners (aryl iodides or diaryliodonium salts) and conditions.",

author = "Bedford, {Robin B.} and Webster, {Ruth L.} and Mitchell, {Charlotte J.}",

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AB - The carbamate (–O2CNR2) function is an excellent directing group for palladium-catalysed direct arylation reactions giving both protected or free mono- or di-substituted phenols, as well as an example of a dibenzopyranone, depending on coupling partners (aryl iodides or diaryliodonium salts) and conditions.

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JO - Organic and Biomolecular Chemistry

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ER -

Palladium-catalysed ortho-arylation of carbamate-protected phenols

Abstract

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