Oxidative conversion of amines into benzoxazoles using hydrogen transfer catalysis

A J Blacker; M M Farah; S P Marsden; O Saidi; J M J Williams

doi:10.1016/j.tetlet.2009.08.042

Oxidative conversion of amines into benzoxazoles using hydrogen transfer catalysis

A J Blacker, M M Farah, S P Marsden, O Saidi, J M J Williams

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

35 Citations (SciVal)

Abstract

Benzoxazoles are synthesised directly by oxidative condensation of primary and secondary amines with o-aminophenols under hydrogen transfer catalysis. The optimal system utilises 1 mol % of the Shvo catalyst, with dimethoxybenzoquinone as the hydrogen-accepting terminal oxidant. (C) 2009 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	6106-6109
Number of pages	4
Journal	Tetrahedron Letters
Volume	50
Issue number	45
DOIs	https://doi.org/10.1016/j.tetlet.2009.08.042
Publication status	Published - 2009

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10.1016/j.tetlet.2009.08.042

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title = "Oxidative conversion of amines into benzoxazoles using hydrogen transfer catalysis",

abstract = "Benzoxazoles are synthesised directly by oxidative condensation of primary and secondary amines with o-aminophenols under hydrogen transfer catalysis. The optimal system utilises 1 mol % of the Shvo catalyst, with dimethoxybenzoquinone as the hydrogen-accepting terminal oxidant. (C) 2009 Elsevier Ltd. All rights reserved.",

author = "Blacker, {A J} and Farah, {M M} and Marsden, {S P} and O Saidi and Williams, {J M J}",

year = "2009",

doi = "10.1016/j.tetlet.2009.08.042",

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pages = "6106--6109",

journal = "Tetrahedron Letters",

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AU - Blacker, A J

AU - Farah, M M

AU - Marsden, S P

AU - Saidi, O

AU - Williams, J M J

PY - 2009

Y1 - 2009

N2 - Benzoxazoles are synthesised directly by oxidative condensation of primary and secondary amines with o-aminophenols under hydrogen transfer catalysis. The optimal system utilises 1 mol % of the Shvo catalyst, with dimethoxybenzoquinone as the hydrogen-accepting terminal oxidant. (C) 2009 Elsevier Ltd. All rights reserved.

AB - Benzoxazoles are synthesised directly by oxidative condensation of primary and secondary amines with o-aminophenols under hydrogen transfer catalysis. The optimal system utilises 1 mol % of the Shvo catalyst, with dimethoxybenzoquinone as the hydrogen-accepting terminal oxidant. (C) 2009 Elsevier Ltd. All rights reserved.

UR - http://www.scopus.com/inward/record.url?scp=70349194522&partnerID=8YFLogxK

UR - http://dx.doi.org/10.1016/j.tetlet.2009.08.042

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DO - 10.1016/j.tetlet.2009.08.042

M3 - Article

SN - 0040-4039

VL - 50

SP - 6106

EP - 6109

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 45

ER -

Oxidative conversion of amines into benzoxazoles using hydrogen transfer catalysis

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Hydrogen Transfer Reactions of Amines

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Oxidative conversion of amines into benzoxazoles using hydrogen transfer catalysis

Abstract

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Hydrogen Transfer Reactions of Amines

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