Oxidative Addition to a Monomeric Stannylene to Give Four-Coordinate Tin Compounds Containing the Bulky Bidentate Ligand C(SiMe3)2SiMe2CH2CH 2Me2Si(Me3Si)2C. Crystal Structures of CH2Me2Si(Me3Si)2CSnC(SiMe 3)2SiMe2CH2

Colin Eaborn; Michael S. Hill; Peter B. Hitchcock; Deepa Patel; J. David Smith; Suobo Zhang

Oxidative Addition to a Monomeric Stannylene to Give Four-Coordinate Tin Compounds Containing the Bulky Bidentate Ligand C(SiMe₃)₂SiMe₂CH₂CH ₂Me₂Si(Me₃Si)₂C. Crystal Structures of CH₂Me₂Si(Me₃Si)₂CSnC(SiMe ₃)₂SiMe₂CH₂

Colin Eaborn
, Michael S. Hill
, Peter B. Hitchcock
, Deepa Patel
, J. David Smith
, Suobo Zhang

University of Sussex

Research output: Contribution to journal › Article › peer-review

46 Citations (SciVal)

Abstract

Reaction of (THF)₂KRRK(THF)₂ (RR = C(SiMe₃)₂SiMe₂CH₂CH ₂Me₂Si(Me₃Si)₂C) with SnCl₂ in Et₂O gave a mixture of the cyclic and linear Sn^II compounds RSnR, 4, and ClSnRRSnCl, 9. This mixture was treated with MeI to give the corresponding SnIV compounds RSnMeIR, 5, and IClMeSnRRSnMeClI, 10. Treatment of 5 and 10 with AgO₂CCF₃ gave the corresponding trifluoroacetates 6 and 11, which were structurally characterized.

Original language	English
Pages (from-to)	49-53
Number of pages	5
Journal	Organometallics
Volume	19
Issue number	1
Publication status	Published - 10 Jan 2000

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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Oxidative Addition to a Monomeric Stannylene to Give Four-Coordinate Tin Compounds Containing the Bulky Bidentate Ligand C(SiMe₃)₂SiMe₂CH₂CH ₂Me₂Si(Me₃Si)₂C. Crystal Structures of CH₂Me₂Si(Me₃Si)₂CSnC(SiMe ₃)₂SiMe₂CH₂. / Eaborn, Colin; Hill, Michael S.; Hitchcock, Peter B. et al.
In: Organometallics, Vol. 19, No. 1, 10.01.2000, p. 49-53.

Research output: Contribution to journal › Article › peer-review

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title = "Oxidative Addition to a Monomeric Stannylene to Give Four-Coordinate Tin Compounds Containing the Bulky Bidentate Ligand C(SiMe3)2SiMe2CH2CH 2Me2Si(Me3Si)2C. Crystal Structures of CH2Me2Si(Me3Si)2CSnC(SiMe 3)2SiMe2CH2",

abstract = "Reaction of (THF)2KRRK(THF)2 (RR = C(SiMe3)2SiMe2CH2CH 2Me2Si(Me3Si)2C) with SnCl2 in Et2O gave a mixture of the cyclic and linear SnII compounds RSnR, 4, and ClSnRRSnCl, 9. This mixture was treated with MeI to give the corresponding SnIV compounds RSnMeIR, 5, and IClMeSnRRSnMeClI, 10. Treatment of 5 and 10 with AgO2CCF3 gave the corresponding trifluoroacetates 6 and 11, which were structurally characterized.",

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T1 - Oxidative Addition to a Monomeric Stannylene to Give Four-Coordinate Tin Compounds Containing the Bulky Bidentate Ligand C(SiMe3)2SiMe2CH2CH 2Me2Si(Me3Si)2C. Crystal Structures of CH2Me2Si(Me3Si)2CSnC(SiMe 3)2SiMe2CH2

AU - Eaborn, Colin

AU - Hill, Michael S.

AU - Hitchcock, Peter B.

AU - Patel, Deepa

AU - Smith, J. David

AU - Zhang, Suobo

PY - 2000/1/10

Y1 - 2000/1/10

N2 - Reaction of (THF)2KRRK(THF)2 (RR = C(SiMe3)2SiMe2CH2CH 2Me2Si(Me3Si)2C) with SnCl2 in Et2O gave a mixture of the cyclic and linear SnII compounds RSnR, 4, and ClSnRRSnCl, 9. This mixture was treated with MeI to give the corresponding SnIV compounds RSnMeIR, 5, and IClMeSnRRSnMeClI, 10. Treatment of 5 and 10 with AgO2CCF3 gave the corresponding trifluoroacetates 6 and 11, which were structurally characterized.

AB - Reaction of (THF)2KRRK(THF)2 (RR = C(SiMe3)2SiMe2CH2CH 2Me2Si(Me3Si)2C) with SnCl2 in Et2O gave a mixture of the cyclic and linear SnII compounds RSnR, 4, and ClSnRRSnCl, 9. This mixture was treated with MeI to give the corresponding SnIV compounds RSnMeIR, 5, and IClMeSnRRSnMeClI, 10. Treatment of 5 and 10 with AgO2CCF3 gave the corresponding trifluoroacetates 6 and 11, which were structurally characterized.

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JO - Organometallics

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