[Os3(CO)9H(SR)], a highly reactive molecule. The X-ray structure of a π-bound ethylene adduct [Os3(CO) 9H(C2H4)(SMe)]

Brian F.G. Johnson; Jack Lewis; David Pippard; Paul R. Raithby

doi:10.1039/C39780000551

[Os₃(CO)₉H(SR)], a highly reactive molecule. The X-ray structure of a π-bound ethylene adduct [Os₃(CO) ₉H(C₂H₄)(SMe)]

Brian F.G. Johnson, Jack Lewis, David Pippard, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The high reactivity of [Os₃(CO)₉H(SR)] (R = Me or Et), associated with a variable co-ordination of the sulphur ligand, has enabled a range of adducts to be prepared; in particular the first X-ray diffraction study of a cluster containing ethylene π-bound to a single metal centre is reported.

Original language	English
Pages (from-to)	551-552
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/C39780000551
Publication status	Published - 31 Dec 1978

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39780000551

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abstract = "The high reactivity of [Os3(CO)9H(SR)] (R = Me or Et), associated with a variable co-ordination of the sulphur ligand, has enabled a range of adducts to be prepared; in particular the first X-ray diffraction study of a cluster containing ethylene π-bound to a single metal centre is reported.",

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AU - Raithby, Paul R.

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AB - The high reactivity of [Os3(CO)9H(SR)] (R = Me or Et), associated with a variable co-ordination of the sulphur ligand, has enabled a range of adducts to be prepared; in particular the first X-ray diffraction study of a cluster containing ethylene π-bound to a single metal centre is reported.

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[Os₃(CO)₉H(SR)], a highly reactive molecule. The X-ray structure of a π-bound ethylene adduct [Os₃(CO) ₉H(C₂H₄)(SMe)]

Abstract

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