Organometallic 'helicopters.' Characterisation of the non-rigid triosmium arene-alkene complexes [Os3(CO)8(η2-CH 2CHR)(μ3-η2:η2: η2-C6H6)], (R=H, Ph) and the X-ray crystal structure of [Os3(CO)8(η2-CH...

Mark A. Gallop; Brian F. G. Johnson; Jack Lewis; Paul R. Raithby

doi:10.1039/C39870001809

Organometallic 'helicopters.' Characterisation of the non-rigid triosmium arene-alkene complexes [Os₃(CO)₈(η²-CH ₂CHR)(μ₃-η²:η²: η²-C₆H₆)], (R=H, Ph) and the X-ray crystal structure of [Os₃(CO)₈(η²-CH...

Mark A. Gallop, Brian F. G. Johnson, Jack Lewis, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

full title:Organometallic 'helicopters.' Characterisation of the non-rigid triosmium arene-alkene complexes [Os₃(CO)₈(η²-CH ₂CHR)(μ₃-η²:η²: η²-C₆H₆)], (R=H, Ph) and the X-ray crystal structure of [Os₃(CO)₈(η²-CH ₂CH₂)(μ_3-η²: η²:η²-C₆H₆)] The cluster-alkene complexes [Os₃(CO)₈(η ²-CH₂CHR)(μ₃-η²: η²:η²-C₆H₆)] (R=H, Ph) contain benzene ligands in a face-capping co-ordination mode, and the geometry of the ethylene derivative has been confirmed by a single-crystal X-ray analysis; the intramolecular dynamics of these complexes have been investigated in solution by n.m.r. spectroscopy and are discussed in terms of arene ring-whizzing and alkene rotation.

Original language	English
Pages (from-to)	1809-1811
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/C39870001809
Publication status	Published - 31 Dec 1987

ASJC Scopus subject areas

Molecular Medicine

Access to Document

10.1039/C39870001809

Fingerprint

Dive into the research topics of 'Organometallic 'helicopters.' Characterisation of the non-rigid triosmium arene-alkene complexes [Os₃(CO)₈(η²-CH ₂CHR)(μ₃-η²:η²: η²-C₆H₆)], (R=H, Ph) and the X-ray crystal structure of [Os₃(CO)₈(η²-CH...'. Together they form a unique fingerprint.

Cite this

Gallop, M. A., Johnson, B. F. G., Lewis, J., & Raithby, P. R. (1987). Organometallic 'helicopters.' Characterisation of the non-rigid triosmium arene-alkene complexes [Os₃(CO)₈(η²-CH ₂CHR)(μ₃-η²:η²: η²-C₆H₆)], (R=H, Ph) and the X-ray crystal structure of [Os₃(CO)₈(η²-CH... Journal of the Chemical Society, Chemical Communications, (24), 1809-1811. https://doi.org/10.1039/C39870001809

Organometallic 'helicopters.' Characterisation of the non-rigid triosmium arene-alkene complexes [Os₃(CO)₈(η²-CH ₂CHR)(μ₃-η²:η²: η²-C₆H₆)], (R=H, Ph) and the X-ray crystal structure of [Os₃(CO)₈(η²-CH... / Gallop, Mark A.; Johnson, Brian F. G.; Lewis, Jack et al.
In: Journal of the Chemical Society, Chemical Communications, No. 24, 31.12.1987, p. 1809-1811.

Research output: Contribution to journal › Article › peer-review

Gallop, MA, Johnson, BFG, Lewis, J & Raithby, PR 1987, 'Organometallic 'helicopters.' Characterisation of the non-rigid triosmium arene-alkene complexes [Os₃(CO)₈(η²-CH ₂CHR)(μ₃-η²:η²: η²-C₆H₆)], (R=H, Ph) and the X-ray crystal structure of [Os₃(CO)₈(η²-CH...', Journal of the Chemical Society, Chemical Communications, no. 24, pp. 1809-1811. https://doi.org/10.1039/C39870001809

@article{a8bf2931a8a34fd7ac86c0622472bd29,

title = "Organometallic 'helicopters.' Characterisation of the non-rigid triosmium arene-alkene complexes [Os3(CO)8(η2-CH 2CHR)(μ3-η2:η2: η2-C6H6)], (R=H, Ph) and the X-ray crystal structure of [Os3(CO)8(η2-CH...",

abstract = "full title:Organometallic 'helicopters.' Characterisation of the non-rigid triosmium arene-alkene complexes [Os3(CO)8(η2-CH 2CHR)(μ3-η2:η2: η2-C6H6)], (R=H, Ph) and the X-ray crystal structure of [Os3(CO)8(η2-CH 2CH2)(μ3-η2: η2:η2-C6H6)] The cluster-alkene complexes [Os3(CO)8(η 2-CH2CHR)(μ3-η2: η2:η2-C6H6)] (R=H, Ph) contain benzene ligands in a face-capping co-ordination mode, and the geometry of the ethylene derivative has been confirmed by a single-crystal X-ray analysis; the intramolecular dynamics of these complexes have been investigated in solution by n.m.r. spectroscopy and are discussed in terms of arene ring-whizzing and alkene rotation.",

author = "Gallop, {Mark A.} and Johnson, {Brian F. G.} and Jack Lewis and Raithby, {Paul R.}",

year = "1987",

month = dec,

day = "31",

doi = "10.1039/C39870001809",

language = "English",

pages = "1809--1811",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "24",

}

TY - JOUR

T1 - Organometallic 'helicopters.' Characterisation of the non-rigid triosmium arene-alkene complexes [Os3(CO)8(η2-CH 2CHR)(μ3-η2:η2: η2-C6H6)], (R=H, Ph) and the X-ray crystal structure of [Os3(CO)8(η2-CH...

AU - Gallop, Mark A.

AU - Johnson, Brian F. G.

AU - Lewis, Jack

AU - Raithby, Paul R.

PY - 1987/12/31

Y1 - 1987/12/31

N2 - full title:Organometallic 'helicopters.' Characterisation of the non-rigid triosmium arene-alkene complexes [Os3(CO)8(η2-CH 2CHR)(μ3-η2:η2: η2-C6H6)], (R=H, Ph) and the X-ray crystal structure of [Os3(CO)8(η2-CH 2CH2)(μ3-η2: η2:η2-C6H6)] The cluster-alkene complexes [Os3(CO)8(η 2-CH2CHR)(μ3-η2: η2:η2-C6H6)] (R=H, Ph) contain benzene ligands in a face-capping co-ordination mode, and the geometry of the ethylene derivative has been confirmed by a single-crystal X-ray analysis; the intramolecular dynamics of these complexes have been investigated in solution by n.m.r. spectroscopy and are discussed in terms of arene ring-whizzing and alkene rotation.

AB - full title:Organometallic 'helicopters.' Characterisation of the non-rigid triosmium arene-alkene complexes [Os3(CO)8(η2-CH 2CHR)(μ3-η2:η2: η2-C6H6)], (R=H, Ph) and the X-ray crystal structure of [Os3(CO)8(η2-CH 2CH2)(μ3-η2: η2:η2-C6H6)] The cluster-alkene complexes [Os3(CO)8(η 2-CH2CHR)(μ3-η2: η2:η2-C6H6)] (R=H, Ph) contain benzene ligands in a face-capping co-ordination mode, and the geometry of the ethylene derivative has been confirmed by a single-crystal X-ray analysis; the intramolecular dynamics of these complexes have been investigated in solution by n.m.r. spectroscopy and are discussed in terms of arene ring-whizzing and alkene rotation.

UR - http://www.scopus.com/inward/record.url?scp=51149203479&partnerID=8YFLogxK

U2 - 10.1039/C39870001809

DO - 10.1039/C39870001809

M3 - Article

AN - SCOPUS:51149203479

SN - 0022-4936

SP - 1809

EP - 1811

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 24

ER -