Organometallic compounds of Group 13 elements containing the ligand C(SiMe 3) 2(SiMe 2C 5H 4N-2)

James Howson; Colin Eaborn; Peter B. Hitchcock; Michael S. Hill; J. David Smith

doi:10.1016/j.jorganchem.2004.08.029

Organometallic compounds of Group 13 elements containing the ligand C(SiMe ₃) ₂(SiMe ₂C ₅H ₄N-2)

James Howson, Colin Eaborn, Peter B. Hitchcock, Michael S. Hill, J. David Smith

Research output: Contribution to journal › Article › peer-review

12 Citations (SciVal)

Abstract

The lithium derivative (1) reacted with AlCl ₃ or Me ₂AlCl to give, respectively, the monomeric compounds (2a) and (2b). The product from reaction with commercially available GaBr ₃ was the analytically pure monomeric heterocycle (3), indicating that the starting halide had been partially hydrolysed before use. The reaction between 1 and commercially available InCl ₃ gave a homogenous white solid (4) with X = Cl (59%) or OH (41%). The X-ray crystal structures of 2a, 3, and 4 have been determined.

Original language	English
Pages (from-to)	69-75
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	690
Issue number	1
DOIs	https://doi.org/10.1016/j.jorganchem.2004.08.029
Publication status	Published - 3 Jan 2005

Funding

The authors thank the EPSRC for financial support.

Keywords

Aluminium
Gallium
Indium
Metallacycles
Organosilicon

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.jorganchem.2004.08.029

Cite this

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title = "Organometallic compounds of Group 13 elements containing the ligand C(SiMe 3) 2(SiMe 2C 5H 4N-2)",

abstract = "The lithium derivative (1) reacted with AlCl 3 or Me 2AlCl to give, respectively, the monomeric compounds (2a) and (2b). The product from reaction with commercially available GaBr 3 was the analytically pure monomeric heterocycle (3), indicating that the starting halide had been partially hydrolysed before use. The reaction between 1 and commercially available InCl 3 gave a homogenous white solid (4) with X = Cl (59\%) or OH (41\%). The X-ray crystal structures of 2a, 3, and 4 have been determined.",

keywords = "Aluminium, Gallium, Indium, Metallacycles, Organosilicon",

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T1 - Organometallic compounds of Group 13 elements containing the ligand C(SiMe 3) 2(SiMe 2C 5H 4N-2)

AU - Howson, James

AU - Eaborn, Colin

AU - Hitchcock, Peter B.

AU - Hill, Michael S.

AU - Smith, J. David

PY - 2005/1/3

Y1 - 2005/1/3

N2 - The lithium derivative (1) reacted with AlCl 3 or Me 2AlCl to give, respectively, the monomeric compounds (2a) and (2b). The product from reaction with commercially available GaBr 3 was the analytically pure monomeric heterocycle (3), indicating that the starting halide had been partially hydrolysed before use. The reaction between 1 and commercially available InCl 3 gave a homogenous white solid (4) with X = Cl (59%) or OH (41%). The X-ray crystal structures of 2a, 3, and 4 have been determined.

AB - The lithium derivative (1) reacted with AlCl 3 or Me 2AlCl to give, respectively, the monomeric compounds (2a) and (2b). The product from reaction with commercially available GaBr 3 was the analytically pure monomeric heterocycle (3), indicating that the starting halide had been partially hydrolysed before use. The reaction between 1 and commercially available InCl 3 gave a homogenous white solid (4) with X = Cl (59%) or OH (41%). The X-ray crystal structures of 2a, 3, and 4 have been determined.

KW - Aluminium

KW - Gallium

KW - Indium

KW - Metallacycles

KW - Organosilicon

UR - https://www.scopus.com/pages/publications/11144298210

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DO - 10.1016/j.jorganchem.2004.08.029

M3 - Article

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VL - 690

SP - 69

EP - 75

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

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ER -