Organometallic compounds of Group 13 elements containing the ligand C(SiMe 3) 2(SiMe 2C 5H 4N-2)

James Howson; Colin Eaborn; Peter B. Hitchcock; Michael S. Hill; J. David Smith

doi:10.1016/j.jorganchem.2004.08.029

Organometallic compounds of Group 13 elements containing the ligand C(SiMe ₃) ₂(SiMe ₂C ₅H ₄N-2)

James Howson, Colin Eaborn, Peter B. Hitchcock, Michael S. Hill, J. David Smith

Research output: Contribution to journal › Article › peer-review

11 Citations (SciVal)

Abstract

The lithium derivative (1) reacted with AlCl ₃ or Me ₂AlCl to give, respectively, the monomeric compounds (2a) and (2b). The product from reaction with commercially available GaBr ₃ was the analytically pure monomeric heterocycle (3), indicating that the starting halide had been partially hydrolysed before use. The reaction between 1 and commercially available InCl ₃ gave a homogenous white solid (4) with X = Cl (59%) or OH (41%). The X-ray crystal structures of 2a, 3, and 4 have been determined.

Original language	English
Pages (from-to)	69-75
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	690
Issue number	1
DOIs	https://doi.org/10.1016/j.jorganchem.2004.08.029
Publication status	Published - 3 Jan 2005

Keywords

Aluminium
Gallium
Indium
Metallacycles
Organosilicon

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.jorganchem.2004.08.029

Cite this

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title = "Organometallic compounds of Group 13 elements containing the ligand C(SiMe 3) 2(SiMe 2C 5H 4N-2)",

abstract = "The lithium derivative (1) reacted with AlCl 3 or Me 2AlCl to give, respectively, the monomeric compounds (2a) and (2b). The product from reaction with commercially available GaBr 3 was the analytically pure monomeric heterocycle (3), indicating that the starting halide had been partially hydrolysed before use. The reaction between 1 and commercially available InCl 3 gave a homogenous white solid (4) with X = Cl (59%) or OH (41%). The X-ray crystal structures of 2a, 3, and 4 have been determined.",

keywords = "Aluminium, Gallium, Indium, Metallacycles, Organosilicon",

author = "James Howson and Colin Eaborn and Hitchcock, {Peter B.} and Hill, {Michael S.} and Smith, {J. David}",

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T1 - Organometallic compounds of Group 13 elements containing the ligand C(SiMe 3) 2(SiMe 2C 5H 4N-2)

AU - Howson, James

AU - Eaborn, Colin

AU - Hitchcock, Peter B.

AU - Hill, Michael S.

AU - Smith, J. David

PY - 2005/1/3

Y1 - 2005/1/3

N2 - The lithium derivative (1) reacted with AlCl 3 or Me 2AlCl to give, respectively, the monomeric compounds (2a) and (2b). The product from reaction with commercially available GaBr 3 was the analytically pure monomeric heterocycle (3), indicating that the starting halide had been partially hydrolysed before use. The reaction between 1 and commercially available InCl 3 gave a homogenous white solid (4) with X = Cl (59%) or OH (41%). The X-ray crystal structures of 2a, 3, and 4 have been determined.

AB - The lithium derivative (1) reacted with AlCl 3 or Me 2AlCl to give, respectively, the monomeric compounds (2a) and (2b). The product from reaction with commercially available GaBr 3 was the analytically pure monomeric heterocycle (3), indicating that the starting halide had been partially hydrolysed before use. The reaction between 1 and commercially available InCl 3 gave a homogenous white solid (4) with X = Cl (59%) or OH (41%). The X-ray crystal structures of 2a, 3, and 4 have been determined.

KW - Aluminium

KW - Gallium

KW - Indium

KW - Metallacycles

KW - Organosilicon

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DO - 10.1016/j.jorganchem.2004.08.029

M3 - Article

AN - SCOPUS:11144298210

SN - 0022-328X

VL - 690

SP - 69

EP - 75

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

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ER -