Organometallic compounds of Group 13 elements containing the ligand C(SiMe 3) 2(SiMe 2C 5H 4N-2)

James Howson, Colin Eaborn, Peter B. Hitchcock, Michael S. Hill, J. David Smith

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

The lithium derivative (1) reacted with AlCl 3 or Me 2AlCl to give, respectively, the monomeric compounds (2a) and (2b). The product from reaction with commercially available GaBr 3 was the analytically pure monomeric heterocycle (3), indicating that the starting halide had been partially hydrolysed before use. The reaction between 1 and commercially available InCl 3 gave a homogenous white solid (4) with X = Cl (59%) or OH (41%). The X-ray crystal structures of 2a, 3, and 4 have been determined.

Original languageEnglish
Pages (from-to)69-75
Number of pages7
JournalJournal of Organometallic Chemistry
Volume690
Issue number1
DOIs
Publication statusPublished - 3 Jan 2005

Keywords

  • Aluminium
  • Gallium
  • Indium
  • Metallacycles
  • Organosilicon

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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