One-pot synthesis of a novel tridentate tin(IV) ligand; syntheses and structures of [BunSn(NC5H4-C,N)3MBr] (M = Li, Cu)

Michael A. Beswick; Clemens J. Belle; Maxwell K. Davies; Malcolm A. Halcrow; Paul R. Raithby; Alexander Steiner; Dominic S. Wright

doi:10.1039/cc9960002619

One-pot synthesis of a novel tridentate tin(IV) ligand; syntheses and structures of [BuⁿSn(NC₅H₄-C,N)₃MBr] (M = Li, Cu)

Michael A. Beswick, Clemens J. Belle, Maxwell K. Davies, Malcolm A. Halcrow, Paul R. Raithby, Alexander Steiner, Dominic S. Wright

University of Cambridge

Research output: Contribution to journal › Article › peer-review

38 Citations (SciVal)

Abstract

During the reaction of [Sn(C₅H₅)₂] with 2-lithiopyridine, further reaction of the [BuⁿBr] byproduct leads to the formation of [BuⁿSn(NC₅H₄-C,N) ₃LiBr]·0.5thf 1, interaction of the tris(pyridyl)tin(IV) ligand of which, with CuCl₂, produces [BuⁿSn(NC₅H₄-C,N) ₃CuBr]·0.5thf 2.

Original language	English
Pages (from-to)	2619-2620
Number of pages	2
Journal	Chemical Communications
Issue number	23
DOIs	https://doi.org/10.1039/cc9960002619
Publication status	Published - 1 Jan 1996

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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@article{65f51837f24f425f998c13cb6b2ec182,

title = "One-pot synthesis of a novel tridentate tin(IV) ligand; syntheses and structures of [BunSn(NC5H4-C,N)3MBr] (M = Li, Cu)",

abstract = "During the reaction of [Sn(C5H5)2] with 2-lithiopyridine, further reaction of the [BunBr] byproduct leads to the formation of [BunSn(NC5H4-C,N) 3LiBr]·0.5thf 1, interaction of the tris(pyridyl)tin(IV) ligand of which, with CuCl2, produces [BunSn(NC5H4-C,N) 3CuBr]·0.5thf 2.",

author = "Beswick, {Michael A.} and Belle, {Clemens J.} and Davies, {Maxwell K.} and Halcrow, {Malcolm A.} and Raithby, {Paul R.} and Alexander Steiner and Wright, {Dominic S.}",

year = "1996",

month = jan,

day = "1",

doi = "10.1039/cc9960002619",

language = "English",

pages = "2619--2620",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "23",

}

TY - JOUR

T1 - One-pot synthesis of a novel tridentate tin(IV) ligand; syntheses and structures of [BunSn(NC5H4-C,N)3MBr] (M = Li, Cu)

AU - Beswick, Michael A.

AU - Belle, Clemens J.

AU - Davies, Maxwell K.

AU - Halcrow, Malcolm A.

AU - Raithby, Paul R.

AU - Steiner, Alexander

AU - Wright, Dominic S.

PY - 1996/1/1

Y1 - 1996/1/1

N2 - During the reaction of [Sn(C5H5)2] with 2-lithiopyridine, further reaction of the [BunBr] byproduct leads to the formation of [BunSn(NC5H4-C,N) 3LiBr]·0.5thf 1, interaction of the tris(pyridyl)tin(IV) ligand of which, with CuCl2, produces [BunSn(NC5H4-C,N) 3CuBr]·0.5thf 2.

AB - During the reaction of [Sn(C5H5)2] with 2-lithiopyridine, further reaction of the [BunBr] byproduct leads to the formation of [BunSn(NC5H4-C,N) 3LiBr]·0.5thf 1, interaction of the tris(pyridyl)tin(IV) ligand of which, with CuCl2, produces [BunSn(NC5H4-C,N) 3CuBr]·0.5thf 2.

UR - http://www.scopus.com/inward/record.url?scp=0002708183&partnerID=8YFLogxK

U2 - 10.1039/cc9960002619

DO - 10.1039/cc9960002619

M3 - Article

AN - SCOPUS:0002708183

SN - 1359-7345

SP - 2619

EP - 2620

JO - Chemical Communications

JF - Chemical Communications

IS - 23

ER -

One-pot synthesis of a novel tridentate tin(IV) ligand; syntheses and structures of [BuⁿSn(NC₅H₄-C,N)₃MBr] (M = Li, Cu)

Abstract

ASJC Scopus subject areas

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