One pot synthesis of a chiral N-phosphine substituted iminophosphorane: X-ray structure and in situ NMR study

Andrei S. Batsanov; Matthew G. Davidson; Ignacio Fernández; Judith A.K. Howard; Fernando López-Ortiz; Richard D. Price

doi:10.1039/b005816p

One pot synthesis of a chiral N-phosphine substituted iminophosphorane: X-ray structure and in situ NMR study

Andrei S. Batsanov, Matthew G. Davidson, Ignacio Fernández, Judith A.K. Howard, Fernando López-Ortiz, Richard D. Price

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

5 Citations (SciVal)

Abstract

An X-ray crystal structure reveals that the attempted deprotonation of cyclopropyl(triphenyl)phosphonium bromide with sodium amide affords a chiral N-phosphine substituted iminophosphorane via an unusual mechanism that has been investigated by multi-nuclear and variable temperature in situ NMR spectroscopy.

Original language	English
Pages (from-to)	4237-4239
Number of pages	3
Journal	Journal of the Chemical Society, Perkin Transactions 1
Issue number	24
DOIs	https://doi.org/10.1039/b005816p
Publication status	Published - 2000

ASJC Scopus subject areas

General Chemistry

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title = "One pot synthesis of a chiral N-phosphine substituted iminophosphorane: X-ray structure and in situ NMR study",

abstract = "An X-ray crystal structure reveals that the attempted deprotonation of cyclopropyl(triphenyl)phosphonium bromide with sodium amide affords a chiral N-phosphine substituted iminophosphorane via an unusual mechanism that has been investigated by multi-nuclear and variable temperature in situ NMR spectroscopy.",

author = "Batsanov, \{Andrei S.\} and Davidson, \{Matthew G.\} and Ignacio Fern{\'a}ndez and Howard, \{Judith A.K.\} and Fernando L{\'o}pez-Ortiz and Price, \{Richard D.\}",

year = "2000",

doi = "10.1039/b005816p",

language = "English",

pages = "4237--4239",

journal = "Journal of the Chemical Society, Perkin Transactions 1",

issn = "1470-4358",

publisher = "Chemical Society",

number = "24",

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T1 - One pot synthesis of a chiral N-phosphine substituted iminophosphorane

T2 - X-ray structure and in situ NMR study

AU - Batsanov, Andrei S.

AU - Davidson, Matthew G.

AU - Fernández, Ignacio

AU - Howard, Judith A.K.

AU - López-Ortiz, Fernando

AU - Price, Richard D.

PY - 2000

Y1 - 2000

N2 - An X-ray crystal structure reveals that the attempted deprotonation of cyclopropyl(triphenyl)phosphonium bromide with sodium amide affords a chiral N-phosphine substituted iminophosphorane via an unusual mechanism that has been investigated by multi-nuclear and variable temperature in situ NMR spectroscopy.

AB - An X-ray crystal structure reveals that the attempted deprotonation of cyclopropyl(triphenyl)phosphonium bromide with sodium amide affords a chiral N-phosphine substituted iminophosphorane via an unusual mechanism that has been investigated by multi-nuclear and variable temperature in situ NMR spectroscopy.

UR - https://www.scopus.com/pages/publications/0034700689

U2 - 10.1039/b005816p

DO - 10.1039/b005816p

M3 - Article

AN - SCOPUS:0034700689

SN - 1470-4358

SP - 4237

EP - 4239

JO - Journal of the Chemical Society, Perkin Transactions 1

JF - Journal of the Chemical Society, Perkin Transactions 1

IS - 24

ER -

One pot synthesis of a chiral N-phosphine substituted iminophosphorane: X-ray structure and in situ NMR study

Abstract

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