Oligo- and Polymerization of Olefins

Randolf Kohn

doi:10.1016/B978-0-08-097774-4.00607-0

Oligo- and Polymerization of Olefins

Randolf Kohn

Department of Chemistry

Research output: Chapter or section in a book/report/conference proceeding › Chapter or section

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Abstract

Metals play an important role in the catalysis of olefin polymerization. This chapter gives an overview of the different mechanistic pathways to polymerization: coordination, metathesis, cationic, anionic, and radical polymerization. The different ways to control the polymer structure, including molecular weight and molecular weight distribution, branching and copolymerization, are outlined. An overview of different olefin monomers used, typical co-catalysts employed, and the use of specific metals in polymerization is given.

Original language	English
Title of host publication	Comprehensive Inorganic Chemistry II
Subtitle of host publication	From Elements to Applications
Publisher	Elsevier
Pages	127-154
Number of pages	28
Volume	6
Edition	2
ISBN (Print)	9780080965291
DOIs	https://doi.org/10.1016/B978-0-08-097774-4.00607-0
Publication status	Published - Aug 2013

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10.1016/B978-0-08-097774-4.00607-0

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abstract = "Metals play an important role in the catalysis of olefin polymerization. This chapter gives an overview of the different mechanistic pathways to polymerization: coordination, metathesis, cationic, anionic, and radical polymerization. The different ways to control the polymer structure, including molecular weight and molecular weight distribution, branching and copolymerization, are outlined. An overview of different olefin monomers used, typical co-catalysts employed, and the use of specific metals in polymerization is given. ",

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AB - Metals play an important role in the catalysis of olefin polymerization. This chapter gives an overview of the different mechanistic pathways to polymerization: coordination, metathesis, cationic, anionic, and radical polymerization. The different ways to control the polymer structure, including molecular weight and molecular weight distribution, branching and copolymerization, are outlined. An overview of different olefin monomers used, typical co-catalysts employed, and the use of specific metals in polymerization is given.

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ER -

Oligo- and Polymerization of Olefins

Abstract

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