Nucleophilic substitution vs. acid-base reactions of [Mn{N(SiMe3)2}2]·2thf; syntheses and structures of

Michael A. Beswick; Christopher N. Harmer; Paul R. Raithby; Alexander Steiner; Kerry L. Verhorevoort; Dominic S. Wright

doi:10.1039/a700765e

Nucleophilic substitution vs. acid-base reactions of [Mn{N(SiMe₃)₂}₂]·2thf; syntheses and structures of

Michael A. Beswick, Christopher N. Harmer, Paul R. Raithby, Alexander Steiner, Kerry L. Verhorevoort, Dominic S. Wright

Research output: Contribution to journal › Article › peer-review

13 Citations (SciVal)

Abstract

The ion-separated complex 2[Li(thf)₄]⁺[Mn(C₁₂H8N)₄] ^2- 1 has been obtained from the nucleophilic substitution reaction of [Mn{N(SiMe₃)₂}₂]·2thf with Li[C₁₂H₈N] (1:4 equivalents) (thf = tetrahydrofuran, C₁₂H₈N = carbazol-9-yl), and the molecular species [Mn(C₁₂H₈N)₂]·3thf 2 from the acid-base reaction of [Mn{N(SiMe₃)₂}₂]·2thf and C₁₂H₈NH (1:2 equivalents). They are among the few amidomanganese(II) complexes containing simple (stericaliy undemanding) dialkyl- or diaryl-amido groups to be characterised. The crystal structures of both were determined: 1 contains the first tetraamidomanganese(II) dianion and 2 possesses the highest co-ordination number for Mn^II in such a compound.

Original language	English
Pages (from-to)	2029-2032
Number of pages	4
Journal	Journal of the Chemical Society - Dalton Transactions
Volume	1997
Issue number	12
DOIs	https://doi.org/10.1039/a700765e
Publication status	Published - 21 Jun 1997

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General Chemistry

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@article{5011fc8bcd2144189ca8afeff32d4c55,

title = "Nucleophilic substitution vs. acid-base reactions of [Mn\{N(SiMe3)2\}2]·2thf; syntheses and structures of",

abstract = "The ion-separated complex 2[Li(thf)4]+[Mn(C12H8N)4] 2- 1 has been obtained from the nucleophilic substitution reaction of [Mn\{N(SiMe3)2\}2]·2thf with Li[C12H8N] (1:4 equivalents) (thf = tetrahydrofuran, C12H8N = carbazol-9-yl), and the molecular species [Mn(C12H8N)2]·3thf 2 from the acid-base reaction of [Mn\{N(SiMe3)2\}2]·2thf and C12H8NH (1:2 equivalents). They are among the few amidomanganese(II) complexes containing simple (stericaliy undemanding) dialkyl- or diaryl-amido groups to be characterised. The crystal structures of both were determined: 1 contains the first tetraamidomanganese(II) dianion and 2 possesses the highest co-ordination number for MnII in such a compound.",

author = "Beswick, \{Michael A.\} and Harmer, \{Christopher N.\} and Raithby, \{Paul R.\} and Alexander Steiner and Verhorevoort, \{Kerry L.\} and Wright, \{Dominic S.\}",

year = "1997",

month = jun,

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doi = "10.1039/a700765e",

language = "English",

volume = "1997",

pages = "2029--2032",

journal = "Journal of the Chemical Society - Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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T1 - Nucleophilic substitution vs. acid-base reactions of [Mn{N(SiMe3)2}2]·2thf; syntheses and structures of

AU - Beswick, Michael A.

AU - Harmer, Christopher N.

AU - Raithby, Paul R.

AU - Steiner, Alexander

AU - Verhorevoort, Kerry L.

AU - Wright, Dominic S.

PY - 1997/6/21

Y1 - 1997/6/21

N2 - The ion-separated complex 2[Li(thf)4]+[Mn(C12H8N)4] 2- 1 has been obtained from the nucleophilic substitution reaction of [Mn{N(SiMe3)2}2]·2thf with Li[C12H8N] (1:4 equivalents) (thf = tetrahydrofuran, C12H8N = carbazol-9-yl), and the molecular species [Mn(C12H8N)2]·3thf 2 from the acid-base reaction of [Mn{N(SiMe3)2}2]·2thf and C12H8NH (1:2 equivalents). They are among the few amidomanganese(II) complexes containing simple (stericaliy undemanding) dialkyl- or diaryl-amido groups to be characterised. The crystal structures of both were determined: 1 contains the first tetraamidomanganese(II) dianion and 2 possesses the highest co-ordination number for MnII in such a compound.

AB - The ion-separated complex 2[Li(thf)4]+[Mn(C12H8N)4] 2- 1 has been obtained from the nucleophilic substitution reaction of [Mn{N(SiMe3)2}2]·2thf with Li[C12H8N] (1:4 equivalents) (thf = tetrahydrofuran, C12H8N = carbazol-9-yl), and the molecular species [Mn(C12H8N)2]·3thf 2 from the acid-base reaction of [Mn{N(SiMe3)2}2]·2thf and C12H8NH (1:2 equivalents). They are among the few amidomanganese(II) complexes containing simple (stericaliy undemanding) dialkyl- or diaryl-amido groups to be characterised. The crystal structures of both were determined: 1 contains the first tetraamidomanganese(II) dianion and 2 possesses the highest co-ordination number for MnII in such a compound.

UR - https://www.scopus.com/pages/publications/33748556285

U2 - 10.1039/a700765e

DO - 10.1039/a700765e

M3 - Article

AN - SCOPUS:33748556285

SN - 0300-9246

VL - 1997

SP - 2029

EP - 2032

JO - Journal of the Chemical Society - Dalton Transactions

JF - Journal of the Chemical Society - Dalton Transactions

IS - 12

ER -

Nucleophilic substitution vs. acid-base reactions of [Mn{N(SiMe₃)₂}₂]·2thf; syntheses and structures of

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