Novel reaction engineering concepts for catalyst immobilisation in hydroformylation

David J. Cole-Hamilton; Simon L. Desset; Ulrich Hintermair; Catherine C. Santini; Mark J. Muldoon

Novel reaction engineering concepts for catalyst immobilisation in hydroformylation

David J. Cole-Hamilton
, Simon L. Desset
, Ulrich Hintermair
, Catherine C. Santini
, Mark J. Muldoon

University of St Andrews
Laboratoire de Chimie Organometallique de Surface
École Supérieure de Chimie Physique Électronique de Lyon

Research output: Contribution to journal › Article › peer-review

1 Citation (SciVal)

Abstract

A discussion covers the different methods for the separation of the aldehyde products from the catalyst and any solvent during or after hydroformylation reactions of long chain alkenes (octene, hexene, pentene); aqueous, fluorous, and ionic liquid biphasic systems as well as systems involving scCO ₂ sometimes in conjunction with one or other of the types of solvents; hybrid systems in which a liquid phase containing the catalyst is supported on a microporous solid support; the advantages and disadvantages of the various systems; new results concerning the addition of [1-octyl-3-methylimidazolium]Br to aqueous biphasic systems and the use of supercritical fluids to transport substrates over supported ionic liquid phases. This is an abstract of a paper presented at the DGMK/SCI-Conference "Synthesis Gas Chemistry" (Dresden, Germany 10/4-6/2006).

Original language	English
Pages (from-to)	41-52
Number of pages	12
Journal	DGMK Tagungsbericht
Issue number	4
Publication status	Published - 1 Dec 2006

ASJC Scopus subject areas

Fuel Technology
Energy Engineering and Power Technology

Cite this

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title = "Novel reaction engineering concepts for catalyst immobilisation in hydroformylation",

abstract = " A discussion covers the different methods for the separation of the aldehyde products from the catalyst and any solvent during or after hydroformylation reactions of long chain alkenes (octene, hexene, pentene); aqueous, fluorous, and ionic liquid biphasic systems as well as systems involving scCO 2 sometimes in conjunction with one or other of the types of solvents; hybrid systems in which a liquid phase containing the catalyst is supported on a microporous solid support; the advantages and disadvantages of the various systems; new results concerning the addition of [1-octyl-3-methylimidazolium]Br to aqueous biphasic systems and the use of supercritical fluids to transport substrates over supported ionic liquid phases. This is an abstract of a paper presented at the DGMK/SCI-Conference {"}Synthesis Gas Chemistry{"} (Dresden, Germany 10/4-6/2006). ",

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T1 - Novel reaction engineering concepts for catalyst immobilisation in hydroformylation

AU - Cole-Hamilton, David J.

AU - Desset, Simon L.

AU - Hintermair, Ulrich

AU - Santini, Catherine C.

AU - Muldoon, Mark J.

PY - 2006/12/1

Y1 - 2006/12/1

N2 - A discussion covers the different methods for the separation of the aldehyde products from the catalyst and any solvent during or after hydroformylation reactions of long chain alkenes (octene, hexene, pentene); aqueous, fluorous, and ionic liquid biphasic systems as well as systems involving scCO 2 sometimes in conjunction with one or other of the types of solvents; hybrid systems in which a liquid phase containing the catalyst is supported on a microporous solid support; the advantages and disadvantages of the various systems; new results concerning the addition of [1-octyl-3-methylimidazolium]Br to aqueous biphasic systems and the use of supercritical fluids to transport substrates over supported ionic liquid phases. This is an abstract of a paper presented at the DGMK/SCI-Conference "Synthesis Gas Chemistry" (Dresden, Germany 10/4-6/2006).

AB - A discussion covers the different methods for the separation of the aldehyde products from the catalyst and any solvent during or after hydroformylation reactions of long chain alkenes (octene, hexene, pentene); aqueous, fluorous, and ionic liquid biphasic systems as well as systems involving scCO 2 sometimes in conjunction with one or other of the types of solvents; hybrid systems in which a liquid phase containing the catalyst is supported on a microporous solid support; the advantages and disadvantages of the various systems; new results concerning the addition of [1-octyl-3-methylimidazolium]Br to aqueous biphasic systems and the use of supercritical fluids to transport substrates over supported ionic liquid phases. This is an abstract of a paper presented at the DGMK/SCI-Conference "Synthesis Gas Chemistry" (Dresden, Germany 10/4-6/2006).

UR - https://www.scopus.com/pages/publications/35448961736

M3 - Article

AN - SCOPUS:35448961736

SN - 1433-9013

SP - 41

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JO - DGMK Tagungsbericht

JF - DGMK Tagungsbericht

IS - 4

ER -

Novel reaction engineering concepts for catalyst immobilisation in hydroformylation

Abstract

ASJC Scopus subject areas

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