Novel pyridyl-stabilised rigid-rod organometallic polymers and their monomeric precursors

Christopher J. Adams; Stuart L. James; Paul R. Raithby

doi:10.1039/a706586h

Novel pyridyl-stabilised rigid-rod organometallic polymers and their monomeric precursors

Christopher J. Adams, Stuart L. James, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

35 Citations (SciVal)

Abstract

Reaction of trans-[Pt(NC₅H₄CHBuⁿ₂) ₂Cl₂] 1 with an excess of HC≡CR (R = Ph, C₆H₄Me, C₆H₄NO₂) affords the monomeric complex trans-[Pt(NC₅H₄CHBuⁿ₂) ₂(C≡CR)₂] (R = Ph 2a, C₆H₄Me 2b, C₆H₄NO₂ 2c), the trans arrangement of the alkynyl ligands being confirmed from spectroscopic data and by an X-ray analysis of 2c; when 1 is treated with 1 equiv. of HC≡CC₆H₂(Me)₂C≡CH the polymer [Pt(NC₅H₄CHBuⁿ₂) ₂C≡CC₆H₂Me₂C≡C] _n is formed, which is soluble in a range of organic solvents.

Original language	English
Pages (from-to)	2155-2156
Number of pages	2
Journal	Chemical Communications
Volume	1997
Issue number	22
DOIs	https://doi.org/10.1039/a706586h
Publication status	Published - 31 Dec 1997

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Novel pyridyl-stabilised rigid-rod organometallic polymers and their monomeric precursors",

abstract = "Reaction of trans-[Pt(NC5H4CHBun2) 2Cl2] 1 with an excess of HC≡CR (R = Ph, C6H4Me, C6H4NO2) affords the monomeric complex trans-[Pt(NC5H4CHBun2) 2(C≡CR)2] (R = Ph 2a, C6H4Me 2b, C6H4NO2 2c), the trans arrangement of the alkynyl ligands being confirmed from spectroscopic data and by an X-ray analysis of 2c; when 1 is treated with 1 equiv. of HC≡CC6H2(Me)2C≡CH the polymer [Pt(NC5H4CHBun2) 2C≡CC6H2Me2C≡C] n is formed, which is soluble in a range of organic solvents.",

author = "Adams, {Christopher J.} and James, {Stuart L.} and Raithby, {Paul R.}",

year = "1997",

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journal = "Chemical Communications",

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T1 - Novel pyridyl-stabilised rigid-rod organometallic polymers and their monomeric precursors

AU - Adams, Christopher J.

AU - James, Stuart L.

AU - Raithby, Paul R.

PY - 1997/12/31

Y1 - 1997/12/31

N2 - Reaction of trans-[Pt(NC5H4CHBun2) 2Cl2] 1 with an excess of HC≡CR (R = Ph, C6H4Me, C6H4NO2) affords the monomeric complex trans-[Pt(NC5H4CHBun2) 2(C≡CR)2] (R = Ph 2a, C6H4Me 2b, C6H4NO2 2c), the trans arrangement of the alkynyl ligands being confirmed from spectroscopic data and by an X-ray analysis of 2c; when 1 is treated with 1 equiv. of HC≡CC6H2(Me)2C≡CH the polymer [Pt(NC5H4CHBun2) 2C≡CC6H2Me2C≡C] n is formed, which is soluble in a range of organic solvents.

AB - Reaction of trans-[Pt(NC5H4CHBun2) 2Cl2] 1 with an excess of HC≡CR (R = Ph, C6H4Me, C6H4NO2) affords the monomeric complex trans-[Pt(NC5H4CHBun2) 2(C≡CR)2] (R = Ph 2a, C6H4Me 2b, C6H4NO2 2c), the trans arrangement of the alkynyl ligands being confirmed from spectroscopic data and by an X-ray analysis of 2c; when 1 is treated with 1 equiv. of HC≡CC6H2(Me)2C≡CH the polymer [Pt(NC5H4CHBun2) 2C≡CC6H2Me2C≡C] n is formed, which is soluble in a range of organic solvents.

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U2 - 10.1039/a706586h

DO - 10.1039/a706586h

M3 - Article

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SN - 1359-7345

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EP - 2156

JO - Chemical Communications

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ER -

Novel pyridyl-stabilised rigid-rod organometallic polymers and their monomeric precursors

Abstract

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