Novel Hybrid Aluminium(III)-Catalen Complexes as Highly Active Catalysts for Lactide Polymerisation: Towards Industrial Relevance

Jack Payne; Matthew Jones; Paul McKeown; Gabriele Kociok-Kohn

doi:10.1039/D0CC02733B

Novel Hybrid Aluminium(III)-Catalen Complexes as Highly Active Catalysts for Lactide Polymerisation: Towards Industrial Relevance

Jack Payne, Matthew Jones, Paul McKeown, Gabriele Kociok-Kohn

Research output: Contribution to journal › Article › peer-review

14 Citations (SciVal)

Abstract

Herein, we report a series of highly active Al(III)-complexes based on a novel hybrid ligand: the catalen. Their application in the production of polylactide under both solution, and industrially preferred melt conditions, is demonstrated. Potential structural diversification to broaden initiator scope is discussed.

Original language	English
Pages (from-to)	7163-7166
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	52
Early online date	22 May 2020
DOIs	https://doi.org/10.1039/D0CC02733B
Publication status	Published - 4 Jul 2020

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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Cite this

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abstract = "Herein, we report a series of highly active Al(III)-complexes based on a novel hybrid ligand: the catalen. Their application in the production of polylactide under both solution, and industrially preferred melt conditions, is demonstrated. Potential structural diversification to broaden initiator scope is discussed.",

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AU - Payne, Jack

AU - Jones, Matthew

AU - McKeown, Paul

AU - Kociok-Kohn, Gabriele

PY - 2020/7/4

Y1 - 2020/7/4

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AB - Herein, we report a series of highly active Al(III)-complexes based on a novel hybrid ligand: the catalen. Their application in the production of polylactide under both solution, and industrially preferred melt conditions, is demonstrated. Potential structural diversification to broaden initiator scope is discussed.

UR - https://www.scopus.com/pages/publications/85087469196

U2 - 10.1039/D0CC02733B

DO - 10.1039/D0CC02733B

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JF - Chemical Communications

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ER -

Novel Hybrid Aluminium(III)-Catalen Complexes as Highly Active Catalysts for Lactide Polymerisation: Towards Industrial Relevance

Abstract

ASJC Scopus subject areas

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