TY - JOUR
T1 - Notes. The synthesis, crystal and molecular structure of a copper(I) complex of 2(1H)-pyridinethione
T2 - An intermediate in Cu4S4 heterocubane build up
AU - Constable, Edwin C.
AU - Raithby, Paul R.
PY - 1987/12/31
Y1 - 1987/12/31
N2 - The reaction of 2(1H)-pyridinethione with copper(II) chloride can give a number of products, one of which is the binuclear complex [Cu2(HL)6]Cl2. The crystal structure of this species reveals each metal atom to be in a near-tetrahedral environment, being bonded to two terminal and two bridging thione ligands. The chloride ions are not bonded to the metal. Treatment of this dimer with base results in the formation of a cubane-like [(CuL)4] cluster.
AB - The reaction of 2(1H)-pyridinethione with copper(II) chloride can give a number of products, one of which is the binuclear complex [Cu2(HL)6]Cl2. The crystal structure of this species reveals each metal atom to be in a near-tetrahedral environment, being bonded to two terminal and two bridging thione ligands. The chloride ions are not bonded to the metal. Treatment of this dimer with base results in the formation of a cubane-like [(CuL)4] cluster.
UR - http://www.scopus.com/inward/record.url?scp=37049068435&partnerID=8YFLogxK
U2 - 10.1039/DT9870002281
DO - 10.1039/DT9870002281
M3 - Article
AN - SCOPUS:37049068435
SN - 1472-7773
SP - 2281
EP - 2283
JO - Journal of the Chemical Society, Dalton Transactions
JF - Journal of the Chemical Society, Dalton Transactions
IS - 9
ER -