Nonacarbonyl(mu(2)-methanethiolato)(mu(3)-trimethyl-silylacetylene triruthenium

O F Koentjoro; H A Sparkes; P R Raithby

doi:10.1107/s1600536806038451

Nonacarbonyl(mu(2)-methanethiolato)(mu(3)-trimethyl-silylacetylene triruthenium

O F Koentjoro, H A Sparkes, P R Raithby

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The structure of the title compound, [Ru-3(mu 2CH3S){mu(3)-C2Si-(CH3)(3)}(CO)(9)], contains an open triangle of Ru atoms. The open edge is bridged on one side by a mu(2)-S(CH3) unit, and the other side of the triangle is capped by a [C CSi(CH3)(3)] group, with the acetylenic bond perpendicular to the open Ru (.) (.) (.) Ru edge.

Original language	English
Pages (from-to)	M3220-M3221
Journal	Acta Crystallographica Section E-Structure Reports Online
Volume	62
DOIs	https://doi.org/10.1107/s1600536806038451
Publication status	Published - 2006

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ID number: ISI:000242434600040

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title = "Nonacarbonyl(mu(2)-methanethiolato)(mu(3)-trimethyl-silylacetylene triruthenium",

abstract = "The structure of the title compound, [Ru-3(mu 2CH3S){mu(3)-C2Si-(CH3)(3)}(CO)(9)], contains an open triangle of Ru atoms. The open edge is bridged on one side by a mu(2)-S(CH3) unit, and the other side of the triangle is capped by a [C CSi(CH3)(3)] group, with the acetylenic bond perpendicular to the open Ru (.) (.) (.) Ru edge.",

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AU - Sparkes, H A

AU - Raithby, P R

N1 - ID number: ISI:000242434600040

PY - 2006

Y1 - 2006

N2 - The structure of the title compound, [Ru-3(mu 2CH3S){mu(3)-C2Si-(CH3)(3)}(CO)(9)], contains an open triangle of Ru atoms. The open edge is bridged on one side by a mu(2)-S(CH3) unit, and the other side of the triangle is capped by a [C CSi(CH3)(3)] group, with the acetylenic bond perpendicular to the open Ru (.) (.) (.) Ru edge.

AB - The structure of the title compound, [Ru-3(mu 2CH3S){mu(3)-C2Si-(CH3)(3)}(CO)(9)], contains an open triangle of Ru atoms. The open edge is bridged on one side by a mu(2)-S(CH3) unit, and the other side of the triangle is capped by a [C CSi(CH3)(3)] group, with the acetylenic bond perpendicular to the open Ru (.) (.) (.) Ru edge.

U2 - 10.1107/s1600536806038451

DO - 10.1107/s1600536806038451

M3 - Article

SN - 1600-5368

VL - 62

SP - M3220-M3221

JO - Acta Crystallographica Section E-Structure Reports Online

JF - Acta Crystallographica Section E-Structure Reports Online

ER -

Nonacarbonyl(mu(2)-methanethiolato)(mu(3)-trimethyl-silylacetylene triruthenium

Abstract

Bibliographical note

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