Projects per year
Reaction of the bulky 6-membered N-heterocyclic carbene 6-Mes with Ni(cod)(2) gives a C-H activated 6-Mes nickel(II) complex, but the novel three-coordinate Ni(I) species Ni(6-Mes)(PPh3)Br if the reaction is performed in the presence of Ni(PPh3)(2)Br-2. The Ni(I) complex is a precursor for the catalytic hydrodehalogenation of aryl halides.
FingerprintDive into the research topics of 'Ni(I) and Ni(II) ring-expanded N-heterocyclic carbene complexes: C-H activation, indole elimination and catalytic hydrodehalogenation'. Together they form a unique fingerprint.
- 2 Finished
12/06/06 → 11/06/09
Project: Research council