Projects per year
Reaction of the bulky 6-membered N-heterocyclic carbene 6-Mes with Ni(cod)(2) gives a C-H activated 6-Mes nickel(II) complex, but the novel three-coordinate Ni(I) species Ni(6-Mes)(PPh3)Br if the reaction is performed in the presence of Ni(PPh3)(2)Br-2. The Ni(I) complex is a precursor for the catalytic hydrodehalogenation of aryl halides.
|Number of pages||3|
|Publication status||Published - 28 Jul 2010|
FingerprintDive into the research topics of 'Ni(I) and Ni(II) ring-expanded N-heterocyclic carbene complexes: C-H activation, indole elimination and catalytic hydrodehalogenation'. Together they form a unique fingerprint.
- 2 Finished
500 MHZ NMR SPECTROMETER TO SUPPORT ORGANIC, BIO-ORGANIC AND INORGANIC CHEMISTRY
Whittlesey, M., Danson, M., Frost, C., Kohn, R., Lowe, J., Weller, A. & Williams, J.
Engineering and Physical Sciences Research Council
12/06/06 → 11/06/09
Project: Research council