New Stable Germylenes, Stannylenes, and Related Compounds II. Bis(butylthio)tin(II) and ate-Complexes [(Me
                        3
                        Si)
                        3
                        CE(μ- SBu)
                        2
                        Li(THF)
                        2
                        ] (E= Ge, Sn). Synthesis and Structure

N. N. Zemlyanskii; I. V. Borisova; M. G. Kuznetsova; E. N. Khrustalev; M. Yu Antipin; Yu A. Ustynyuk; E. E. Lunin; C. Eaborn; M. S. Hill; J. D. Smith

doi:10.1023/A:1026051616477

New Stable Germylenes, Stannylenes, and Related Compounds II. Bis(butylthio)tin(II) and ate-Complexes [(Me ₃ Si) ₃ CE(μ- SBu) ₂ Li(THF) ₂ ] (E= Ge, Sn). Synthesis and Structure

N. N. Zemlyanskii, I. V. Borisova, M. G. Kuznetsova, E. N. Khrustalev, M. Yu Antipin, Yu A. Ustynyuk, E. E. Lunin, C. Eaborn, M. S. Hill, J. D. Smith

Research output: Contribution to journal › Article › peer-review

7 Citations (SciVal)

Abstract

By reaction of Me ₃ SiSBu with anhydrous tin(II) chloride bis(butylthio)tin was obtained that exemplified a coordination polymer [Sn(SBu) ₂ ] _n , whose elementary unit contained according to X-ray diffraction study three independent four-membered rings Sn ₂ S ₂ of unusual geometry. It was demonstrated that polymeric thiolates [E(SBu) ₂ ] _n , (E = Ge, Sn) readily reacted with TsiLi (Tsi = C(SiMe ₃ ) ₃ ) in a mixed solvent ether THF affording in a good yield ate-complexes [(Me ₃ Si) ₃ CE(μ-SBu) ₂ Li(THF) ₂ ]. Both complexes contain a four-membered ring in a butterfly conformation where the lithium atom is symmetrically bonded to both sulfur atoms, and the coordination polyhedra of Ge and Sn atoms may be regarded as distorted tetrahedra AB ₃ X, where one of coordination places is occupied by unshared electron pair. The structure of the ate-complexes observed in a crystal is conserved also in solution of nonpolar solvents.

Original language	English
Pages (from-to)	491-500
Number of pages	10
Journal	Russian Journal of Organic Chemistry
Volume	39
Issue number	4
DOIs	https://doi.org/10.1023/A:1026051616477
Publication status	Published - 1 Apr 2003

Funding

The study was carried out under financial support of the Russian Foundation for Basic Research (grants nos. 00-03-32807a, 00-15-97359, and 00-03-32889).

ASJC Scopus subject areas

Organic Chemistry

Access to Document

10.1023/A:1026051616477

Cite this

Zemlyanskii, N. N., Borisova, I. V., Kuznetsova, M. G., Khrustalev, E. N., Antipin, M. Y., Ustynyuk, Y. A., Lunin, E. E., Eaborn, C., Hill, M. S., & Smith, J. D. (2003). New Stable Germylenes, Stannylenes, and Related Compounds II. Bis(butylthio)tin(II) and ate-Complexes [(Me ₃ Si) ₃ CE(μ- SBu) ₂ Li(THF) ₂ ] (E= Ge, Sn). Synthesis and Structure. Russian Journal of Organic Chemistry, 39(4), 491-500. https://doi.org/10.1023/A:1026051616477

New Stable Germylenes, Stannylenes, and Related Compounds II. Bis(butylthio)tin(II) and ate-Complexes [(Me ₃ Si) ₃ CE(μ- SBu) ₂ Li(THF) ₂ ] (E= Ge, Sn). Synthesis and Structure. / Zemlyanskii, N. N.; Borisova, I. V.; Kuznetsova, M. G. et al.
In: Russian Journal of Organic Chemistry, Vol. 39, No. 4, 01.04.2003, p. 491-500.

Research output: Contribution to journal › Article › peer-review

Zemlyanskii, NN, Borisova, IV, Kuznetsova, MG, Khrustalev, EN, Antipin, MY, Ustynyuk, YA, Lunin, EE, Eaborn, C, Hill, MS & Smith, JD 2003, 'New Stable Germylenes, Stannylenes, and Related Compounds II. Bis(butylthio)tin(II) and ate-Complexes [(Me ₃ Si) ₃ CE(μ- SBu) ₂ Li(THF) ₂ ] (E= Ge, Sn). Synthesis and Structure', Russian Journal of Organic Chemistry, vol. 39, no. 4, pp. 491-500. https://doi.org/10.1023/A:1026051616477

Zemlyanskii NN, Borisova IV, Kuznetsova MG, Khrustalev EN, Antipin MY, Ustynyuk YA et al. New Stable Germylenes, Stannylenes, and Related Compounds II. Bis(butylthio)tin(II) and ate-Complexes [(Me ₃ Si) ₃ CE(μ- SBu) ₂ Li(THF) ₂ ] (E= Ge, Sn). Synthesis and Structure. Russian Journal of Organic Chemistry. 2003 Apr 1;39(4):491-500. doi: 10.1023/A:1026051616477

Zemlyanskii, N. N. ; Borisova, I. V. ; Kuznetsova, M. G. et al. / New Stable Germylenes, Stannylenes, and Related Compounds II. Bis(butylthio)tin(II) and ate-Complexes [(Me ₃ Si) ₃ CE(μ- SBu) ₂ Li(THF) ₂ ] (E= Ge, Sn). Synthesis and Structure. In: Russian Journal of Organic Chemistry. 2003 ; Vol. 39, No. 4. pp. 491-500.

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title = "New Stable Germylenes, Stannylenes, and Related Compounds II. Bis(butylthio)tin(II) and ate-Complexes [(Me 3 Si) 3 CE(μ- SBu) 2 Li(THF) 2 ] (E= Ge, Sn). Synthesis and Structure",

abstract = " By reaction of Me 3 SiSBu with anhydrous tin(II) chloride bis(butylthio)tin was obtained that exemplified a coordination polymer [Sn(SBu) 2 ] n , whose elementary unit contained according to X-ray diffraction study three independent four-membered rings Sn 2 S 2 of unusual geometry. It was demonstrated that polymeric thiolates [E(SBu) 2 ] n , (E = Ge, Sn) readily reacted with TsiLi (Tsi = C(SiMe 3 ) 3 ) in a mixed solvent ether THF affording in a good yield ate-complexes [(Me 3 Si) 3 CE(μ-SBu) 2 Li(THF) 2 ]. Both complexes contain a four-membered ring in a butterfly conformation where the lithium atom is symmetrically bonded to both sulfur atoms, and the coordination polyhedra of Ge and Sn atoms may be regarded as distorted tetrahedra AB 3 X, where one of coordination places is occupied by unshared electron pair. The structure of the ate-complexes observed in a crystal is conserved also in solution of nonpolar solvents. ",

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N2 - By reaction of Me 3 SiSBu with anhydrous tin(II) chloride bis(butylthio)tin was obtained that exemplified a coordination polymer [Sn(SBu) 2 ] n , whose elementary unit contained according to X-ray diffraction study three independent four-membered rings Sn 2 S 2 of unusual geometry. It was demonstrated that polymeric thiolates [E(SBu) 2 ] n , (E = Ge, Sn) readily reacted with TsiLi (Tsi = C(SiMe 3 ) 3 ) in a mixed solvent ether THF affording in a good yield ate-complexes [(Me 3 Si) 3 CE(μ-SBu) 2 Li(THF) 2 ]. Both complexes contain a four-membered ring in a butterfly conformation where the lithium atom is symmetrically bonded to both sulfur atoms, and the coordination polyhedra of Ge and Sn atoms may be regarded as distorted tetrahedra AB 3 X, where one of coordination places is occupied by unshared electron pair. The structure of the ate-complexes observed in a crystal is conserved also in solution of nonpolar solvents.

AB - By reaction of Me 3 SiSBu with anhydrous tin(II) chloride bis(butylthio)tin was obtained that exemplified a coordination polymer [Sn(SBu) 2 ] n , whose elementary unit contained according to X-ray diffraction study three independent four-membered rings Sn 2 S 2 of unusual geometry. It was demonstrated that polymeric thiolates [E(SBu) 2 ] n , (E = Ge, Sn) readily reacted with TsiLi (Tsi = C(SiMe 3 ) 3 ) in a mixed solvent ether THF affording in a good yield ate-complexes [(Me 3 Si) 3 CE(μ-SBu) 2 Li(THF) 2 ]. Both complexes contain a four-membered ring in a butterfly conformation where the lithium atom is symmetrically bonded to both sulfur atoms, and the coordination polyhedra of Ge and Sn atoms may be regarded as distorted tetrahedra AB 3 X, where one of coordination places is occupied by unshared electron pair. The structure of the ate-complexes observed in a crystal is conserved also in solution of nonpolar solvents.

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