New challenge for classics: Neutral zinc complexes stabilised by 2,2'-bipyridine and 1,10-phenanthroline and their application in the ring-opening polymerisation of lactide

Janna Börner, Ulrich Flörke, Artjom Döring, Dirk Kuckling, Matthew D. Jones, Sonja Herres-Pawlis

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

The zinc acetato and triflato complexes of 2,2'-bipyridine and 1,10-phenanthroline were prepared and completely characterised. The whole series (including the already described dichlorido complexes and the ligands themselves) were screened for their catalytic activity in the solvent free ring-opening polymerisation of D,L-lactide. The acetato and triflato complexes were found to be active initiators and polylactides could be obtained in almost quantitative yields or with high molecular weights, up to 145,000 g/mol.

Original languageEnglish
Pages (from-to)1226-1239
Number of pages14
JournalSustainability
Volume1
Issue number4
DOIs
Publication statusPublished - 1 Dec 2009

Keywords

  • Biopolymers
  • Lactide
  • N-donor ligands
  • Ring-opening polymerisation
  • Sustainable chemistry
  • Zinc

ASJC Scopus subject areas

  • Geography, Planning and Development
  • Renewable Energy, Sustainability and the Environment
  • Management, Monitoring, Policy and Law

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