Projects per year
Abstract
[K{Al(NON Dipp )}] 2 (NON Dipp = [O(SiMe 2 NDipp) 2 ] 2– , Dipp = 2,6‐ i Pr 2 C 6 H 3 ) reacts with CS 2 to afford the trithiocarbonate species [K(OEt 2 )][Al(NON Dipp )(CS 3 )] 1 or the ethenetetrathiolate complex, [K{Al(NON Dipp )(S 2 C)}] 2 [ 3 ] 2 . The dimeric alumoxane [K{Al(NON Dipp )(O)}] 2 reacts with carbon monoxide to afford the oxygen analogue of 3 , [K{Al(NON Dipp )(O 2 C)}] 2 [ 4 ] 2 containing the hitherto unknown ethenetetraolate ligand, [C 2 O 4 ] 4– .
Original language | English |
---|---|
Journal | Angewandte Chemie - International Edition |
Early online date | 6 May 2020 |
DOIs | |
Publication status | Published - 2 Jun 2020 |
Funding
This research made use of the Balena High Performance Computing (HPC) Service at the University of Bath.
Fingerprint
Dive into the research topics of 'New Carbon‐Carbon Bond Forming Reactions Promoted by Aluminyl and Alumoxane Anions: Introducing the Ethenetetraolate Ligand'. Together they form a unique fingerprint.Projects
- 1 Finished
-
Nucleophilic alkaline earth boryls: from conception and theory to application
Hill, M. (PI), Cresswell, A. (CoI) & McMullin, C. (Researcher)
Engineering and Physical Sciences Research Council
1/05/18 → 31/07/22
Project: Research council
Equipment
-
Balena High Performance Computing (HPC) System
Facility/equipment: Equipment