New Carbon‐Carbon Bond Forming Reactions Promoted by Aluminyl and Alumoxane Anions: Introducing the Ethenetetraolate Ligand

Claire McMullin; Nasir Rajabi; Mathew Anker; Martyn Coles

doi:10.1002/anie.202005301

New Carbon‐Carbon Bond Forming Reactions Promoted by Aluminyl and Alumoxane Anions: Introducing the Ethenetetraolate Ligand

Claire McMullin, Nasir Rajabi, Mathew Anker, Martyn Coles

Department of Chemistry

Victoria University of Wellington

Research output: Contribution to journal › Article › peer-review

38 Citations (SciVal)

94 Downloads (Pure)

Abstract

[K{Al(NON Dipp )}] 2 (NON Dipp = [O(SiMe 2 NDipp) 2 ] 2– , Dipp = 2,6‐ i Pr 2 C 6 H 3 ) reacts with CS 2 to afford the trithiocarbonate species [K(OEt 2 )][Al(NON Dipp )(CS 3 )] 1 or the ethenetetrathiolate complex, [K{Al(NON Dipp )(S 2 C)}] 2 [ 3 ] 2 . The dimeric alumoxane [K{Al(NON Dipp )(O)}] 2 reacts with carbon monoxide to afford the oxygen analogue of 3 , [K{Al(NON Dipp )(O 2 C)}] 2 [ 4 ] 2 containing the hitherto unknown ethenetetraolate ligand, [C 2 O 4 ] 4– .

Original language	English
Journal	Angewandte Chemie - International Edition
Early online date	6 May 2020
DOIs	https://doi.org/10.1002/anie.202005301
Publication status	Published - 2 Jun 2020

Funding

This research made use of the Balena High Performance Computing (HPC) Service at the University of Bath.

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10.1002/anie.202005301

Corrected_CS2 (1).PDF
This is the peer reviewed version of the following article: Anker, M..D., McMullin, C., Rajabi, N..A. and Coles, M..P. (2020), New Carbon‐Carbon Bond Forming Reactions Promoted by Aluminyl and Alumoxane Anions: Introducing the Ethenetetraolate Ligand. Angew. Chem. Int. Ed.. Accepted Author Manuscript, which has been published in final form at https://doi.org/10.1002/anie.202005301. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
Accepted author manuscript, 887 KB

Nucleophilic alkaline earth boryls: from conception and theory to application
Hill, M. (PI), Cresswell, A. (CoI) & McMullin, C. (Researcher)
Engineering and Physical Sciences Research Council
1/05/18 → 31/07/22
Project: Research council

Balena High Performance Computing (HPC) System
Facility/equipment: Equipment

Cite this

@article{bd254fca4c114600aecff7c19ebcd787,

title = "New Carbon‐Carbon Bond Forming Reactions Promoted by Aluminyl and Alumoxane Anions: Introducing the Ethenetetraolate Ligand",

abstract = "[K{Al(NON Dipp )}] 2 (NON Dipp = [O(SiMe 2 NDipp) 2 ] 2– , Dipp = 2,6‐ i Pr 2 C 6 H 3 ) reacts with CS 2 to afford the trithiocarbonate species [K(OEt 2 )][Al(NON Dipp )(CS 3 )] 1 or the ethenetetrathiolate complex, [K{Al(NON Dipp )(S 2 C)}] 2 [ 3 ] 2 . The dimeric alumoxane [K{Al(NON Dipp )(O)}] 2 reacts with carbon monoxide to afford the oxygen analogue of 3 , [K{Al(NON Dipp )(O 2 C)}] 2 [ 4 ] 2 containing the hitherto unknown ethenetetraolate ligand, [C 2 O 4 ] 4– .",

author = "Claire McMullin and Nasir Rajabi and Mathew Anker and Martyn Coles",

year = "2020",

month = jun,

day = "2",

doi = "10.1002/anie.202005301",

language = "English",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Inc.",

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T1 - New Carbon‐Carbon Bond Forming Reactions Promoted by Aluminyl and Alumoxane Anions: Introducing the Ethenetetraolate Ligand

AU - McMullin, Claire

AU - Rajabi, Nasir

AU - Anker, Mathew

AU - Coles, Martyn

PY - 2020/6/2

Y1 - 2020/6/2

N2 - [K{Al(NON Dipp )}] 2 (NON Dipp = [O(SiMe 2 NDipp) 2 ] 2– , Dipp = 2,6‐ i Pr 2 C 6 H 3 ) reacts with CS 2 to afford the trithiocarbonate species [K(OEt 2 )][Al(NON Dipp )(CS 3 )] 1 or the ethenetetrathiolate complex, [K{Al(NON Dipp )(S 2 C)}] 2 [ 3 ] 2 . The dimeric alumoxane [K{Al(NON Dipp )(O)}] 2 reacts with carbon monoxide to afford the oxygen analogue of 3 , [K{Al(NON Dipp )(O 2 C)}] 2 [ 4 ] 2 containing the hitherto unknown ethenetetraolate ligand, [C 2 O 4 ] 4– .

AB - [K{Al(NON Dipp )}] 2 (NON Dipp = [O(SiMe 2 NDipp) 2 ] 2– , Dipp = 2,6‐ i Pr 2 C 6 H 3 ) reacts with CS 2 to afford the trithiocarbonate species [K(OEt 2 )][Al(NON Dipp )(CS 3 )] 1 or the ethenetetrathiolate complex, [K{Al(NON Dipp )(S 2 C)}] 2 [ 3 ] 2 . The dimeric alumoxane [K{Al(NON Dipp )(O)}] 2 reacts with carbon monoxide to afford the oxygen analogue of 3 , [K{Al(NON Dipp )(O 2 C)}] 2 [ 4 ] 2 containing the hitherto unknown ethenetetraolate ligand, [C 2 O 4 ] 4– .

U2 - 10.1002/anie.202005301

DO - 10.1002/anie.202005301

M3 - Article

SN - 1433-7851

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

ER -

New Carbon‐Carbon Bond Forming Reactions Promoted by Aluminyl and Alumoxane Anions: Introducing the Ethenetetraolate Ligand

Abstract

Funding

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Projects

Nucleophilic alkaline earth boryls: from conception and theory to application

Equipment

Balena High Performance Computing (HPC) System

Cite this