TY - JOUR
T1 - Negative thermal expansion in ZrW2O4
T2 - Mechanisms, rigid unit modes, and neutron total scattering
AU - Tucker, M.G.
AU - Goodwin, A.L.
AU - Dove, M.T.
AU - Keen, D.A.
AU - Wells, S.A.
AU - Evans, J.S.O.
PY - 2005/12/16
Y1 - 2005/12/16
N2 - The local structure of the low-temperature ordered phase of the negative thermal expansion (NTE) material ZrW2O8 has been investigated by reverse Monte Carlo (RMC) modeling of neutron total scattering data. We obtain, for the first time, quantitative measurements of the extent to which the WO4 and ZrO6 polyhedra move as rigid units, and we show that these values are consistent with the predictions of rigid unit mode theory. We suggest that rigid unit modes are associated with the NTE. Our results do not support a recent interpretation of x-ray-absorption fine structure spectroscopy data in terms of a larger rigid structural component involving the Zr-O-W linkage.
AB - The local structure of the low-temperature ordered phase of the negative thermal expansion (NTE) material ZrW2O8 has been investigated by reverse Monte Carlo (RMC) modeling of neutron total scattering data. We obtain, for the first time, quantitative measurements of the extent to which the WO4 and ZrO6 polyhedra move as rigid units, and we show that these values are consistent with the predictions of rigid unit mode theory. We suggest that rigid unit modes are associated with the NTE. Our results do not support a recent interpretation of x-ray-absorption fine structure spectroscopy data in terms of a larger rigid structural component involving the Zr-O-W linkage.
UR - http://www.scopus.com/inward/record.url?scp=29144444420&partnerID=8YFLogxK
UR - http://dx.doi.org/10.1103/PhysRevLett.95.255501
U2 - 10.1103/PhysRevLett.95.255501
DO - 10.1103/PhysRevLett.95.255501
M3 - Article
AN - SCOPUS:29144444420
SN - 0031-9007
VL - 95
JO - Physical Review Letters
JF - Physical Review Letters
IS - 25
M1 - 255501
ER -