Abstract
People of all ages consume salt every day, but is it really just salt? Plastic nanoparticles [nanoplastics (NPs)] pose an increasing environmental threat and have begun to contaminate everyday salt in consumer goods. Herein, we developed a combined surface enhanced Raman scattering (SERS) and stimulated Raman scattering (SRS) approach that can realize the filtration, enrichment, and detection of NPs in commercial salt. The Au-loaded (50 nm) anodic alumina oxide substrate was used as the SERS substrate to explore the potential types of NP contaminants in salts. SRS was used to conduct imaging and quantify the presence of the NPs. SRS detection was successfully established through standard plastics, and NPs were identified through the match of the hydrocarbon group of the nanoparticles. Simultaneously, the NPs were quantified based on the high spatial resolution and rapid imaging of the SRS imaging platform. NPs in sea salts produced in Asia, Australasia, Europe, and the Atlantic were studied. We estimate that, depending on the location, an average person could be ingesting as many as 6 million NPs per year through the consumption of sea salt alone. The potential health hazards associated with NP ingestion should not be underestimated.
Original language | English |
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Pages (from-to) | 9091-9101 |
Number of pages | 11 |
Journal | Environmental Science and Technology |
Volume | 58 |
Issue number | 21 |
Early online date | 6 May 2024 |
DOIs | |
Publication status | Published - 28 May 2024 |
Funding
We are grateful to Marco Centini for providing sea salt from Italy and to Ane\u0301lia Ve\u0301le\u0301va-Fath for providing the sea salt from France. The authors gratefully acknowledge financial support from the National Natural Science Foundation of China (nos. 22176036, 21976030, and 22006020) and the Natural Science Foundation of Shanghai (no. 19ZR1471200). V.K.V. acknowledges support from the Royal Society through the University Research Fellowships and the Royal Society grants PEF1\\170015 and RGF\\EA\\180228, as well as the EPSRC grant EP/T001046/1. V.K.V. and L.Z. acknowledge the International Collaboration Awards 2020 of the Royal Society (no. ICA\\R1\\201088).
Funders | Funder number |
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Natural Science Foundation of Shanghai Municipality | 19ZR1471200 |
Natural Science Foundation of Shanghai Municipality | |
Royal Society | RGF\EA\180228, PEF1\170015 |
Royal Society | |
Engineering and Physical Sciences Research Council | EP/T001046/1 |
Engineering and Physical Sciences Research Council | |
National Natural Science Foundation of China | 22006020, 22176036, 21976030 |
National Natural Science Foundation of China |
Keywords
- nanoplastics
- sea salt
- SERS
- SRS
ASJC Scopus subject areas
- General Chemistry
- Environmental Chemistry
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Dataset for "Nanoplastics Detected in Commercial Sea Salt"
Ruan, X. (Creator), Ao, J. (Creator), Jones, R. (Creator), Liu, J. (Creator), Xu, G. (Creator), Xie, L. (Creator), Li, K. (Creator), Gong, K. (Creator), Wang, W. (Creator), Valev, V. (Creator), Ji, M. (Creator) & Zhang, L. (Creator), University of Bath, 29 May 2024
DOI: 10.15125/BATH-01140
Dataset