Mutual Insight on Ferroelectrics and Hybrid Halide Perovskites: A Platform for Future Multifunctional Energy Conversion

Richa Pandey, Gaurav Vats, Jae Yun, Chris R. Bowen, Anita W.Y. Ho-Baillie, Jan Seidel, Keith Tobias Butler, Sang Il Seok

Research output: Contribution to journalReview article

3 Citations (Scopus)

Abstract

An insight into the analogies, state-of-the-art technologies, concepts, and prospects under the umbrella of perovskite materials (both inorganic–organic hybrid halide perovskites and ferroelectric perovskites) for future multifunctional energy conversion and storage devices is provided. Often, these are considered entirely different branches of research; however, considering them simultaneously and holistically can provide several new opportunities. Recent advancements have highlighted the potential of hybrid perovskites for high-efficiency solar cells. The intrinsic polar properties of these materials, including the potential for ferroelectricity, provide additional possibilities for simultaneously exploiting several energy conversion mechanisms such as the piezoelectric, pyroelectric, and thermoelectric effect and electrical energy storage. The presence of these phenomena can support the performance of perovskite solar cells. The energy conversion using these effects (piezo-, pyro-, and thermoelectric effect) can also be enhanced by a change in the light intensity. Thus, there lies a range of possibilities for tuning the structural, electronic, optical, and magnetic properties of perovskites to simultaneously harvest energy using more than one mechanism to realize an improved efficiency. This requires a basic understanding of concepts, mechanisms, corresponding material properties, and the underlying physics involved with these effects.

Original languageEnglish
Article number1807376
Pages (from-to)1-26
Number of pages26
JournalAdvanced Materials
Volume31
Issue number43
Early online date22 Aug 2019
DOIs
Publication statusPublished - 25 Oct 2019

Keywords

  • energy storage
  • ferroelectrics
  • perovskites
  • photoferroic effect
  • pyroelectric effect
  • thermoelectric effect

ASJC Scopus subject areas

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

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