Multi-mode self-healing in composite materials using novel chemistry

Ian Bond, Tim Coope, Richard Trask, Greg McCombe, Duncan Wass, Ulrich Mayer

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

A novel Lewis acid-catalysed self-healing system is investigated for implementation in epoxy-based fibre reinforced polymer (FRP) composite materials. The catalyst, scandium(III) triflate, is selected using a qualitative approach and subsequently embedded with pre-synthesised epoxy-solvent loaded microcapsules, into an epoxy resin. Healing is initiated when microcapsules are ruptured at the onset of crack propagation. The epoxy monomer healing agent contained within, actively undergoes ring-opening polymerisation (ROP) on contact with the locally placed catalyst, forming a new polymer to bridge the two fractured crack surfaces. Self-healing performance is quantified using tapered double cantilever beam (TDCB) epoxy resin test specimens and the effects of microcapsule loading, microcapsule content and healing temperature are all independently considered. As an initial proof of concept study, results show that a material recovery value of greater than 80% fracture strength is achieved for this novel Lewis acid-catalysed self-healing epoxy resin. The same self-healing agent system was subsequently demonstrated in a larger scale FRP component by incorporating both a microcapsule and hollow glass fibre (HGF) delivery system within an FRP laminate using a End-Notched Flexure (ENF) test configuration.

Original languageEnglish
Title of host publicationASME 2011 Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS 2011
Pages25-31
Number of pages7
Volume1
Publication statusPublished - 2011
EventASME 2011 Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS 2011 - Scottsdale, AZ, USA United States
Duration: 18 Sep 201121 Sep 2011

Conference

ConferenceASME 2011 Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS 2011
CountryUSA United States
CityScottsdale, AZ
Period18/09/1121/09/11

Fingerprint

Capsules
Epoxy Resins
Epoxy resins
Polymers
Composite materials
Lewis Acids
Fibers
Scandium
Catalysts
Acids
Ring opening polymerization
Cantilever beams
Glass fibers
Laminates
Fracture toughness
Crack propagation
Monomers
Cracks
Recovery
Temperature

ASJC Scopus subject areas

  • Civil and Structural Engineering
  • Biomaterials

Cite this

Bond, I., Coope, T., Trask, R., McCombe, G., Wass, D., & Mayer, U. (2011). Multi-mode self-healing in composite materials using novel chemistry. In ASME 2011 Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS 2011 (Vol. 1, pp. 25-31)

Multi-mode self-healing in composite materials using novel chemistry. / Bond, Ian; Coope, Tim; Trask, Richard; McCombe, Greg; Wass, Duncan; Mayer, Ulrich.

ASME 2011 Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS 2011. Vol. 1 2011. p. 25-31.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Bond, I, Coope, T, Trask, R, McCombe, G, Wass, D & Mayer, U 2011, Multi-mode self-healing in composite materials using novel chemistry. in ASME 2011 Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS 2011. vol. 1, pp. 25-31, ASME 2011 Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS 2011, Scottsdale, AZ, USA United States, 18/09/11.
Bond I, Coope T, Trask R, McCombe G, Wass D, Mayer U. Multi-mode self-healing in composite materials using novel chemistry. In ASME 2011 Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS 2011. Vol. 1. 2011. p. 25-31
Bond, Ian ; Coope, Tim ; Trask, Richard ; McCombe, Greg ; Wass, Duncan ; Mayer, Ulrich. / Multi-mode self-healing in composite materials using novel chemistry. ASME 2011 Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS 2011. Vol. 1 2011. pp. 25-31
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