Monomeric Group 13 compounds with bidentate (N, O) ligands

Michael S. Hill; Aaron R. Hutchison; Timothy S. Keizer; Sean Parkin; Michael A. Vanaelstyn; David A. Atwood

doi:10.1016/S0022-328X(01)00738-0

Monomeric Group 13 compounds with bidentate (N, O) ligands

Michael S. Hill, Aaron R. Hutchison, Timothy S. Keizer, Sean Parkin, Michael A. Vanaelstyn, David A. Atwood

University of Kentucky

Research output: Contribution to journal › Article › peer-review

28 Citations (SciVal)

Abstract

The bidentate ligand, Sal(^tBu)H, is prepared by the condensation of one equivalent of a bulky amine with 3,-5-di-tert-butylsalicylaldehyde. When one equivalent of Sal(^tBu)H is added to MR₃ or AlMe₂Cl, compounds are btained which have the general form: [Sal(^tBu)MR₂] (with M/R combinations, Al/Me (1), Al/Et (3), Ga/Et (4) and In/Et (5)) and Sal(^tBu)AlMeCl (2). The compounds are characterized by melting point, elemental analyses, IR, ¹H-NMR, and in the case of 2 and 3 by single-crystal X-ray analysis.

Original language	English
Pages (from-to)	71-75
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	628
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(01)00738-0
Publication status	Published - 15 May 2001

Keywords

Aluminum
Chelate
Gallium

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-328X(01)00738-0

Cite this

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title = "Monomeric Group 13 compounds with bidentate (N, O) ligands",

abstract = "The bidentate ligand, Sal(tBu)H, is prepared by the condensation of one equivalent of a bulky amine with 3,-5-di-tert-butylsalicylaldehyde. When one equivalent of Sal(tBu)H is added to MR3 or AlMe2Cl, compounds are btained which have the general form: [Sal(tBu)MR2] (with M/R combinations, Al/Me (1), Al/Et (3), Ga/Et (4) and In/Et (5)) and Sal(tBu)AlMeCl (2). The compounds are characterized by melting point, elemental analyses, IR, 1H-NMR, and in the case of 2 and 3 by single-crystal X-ray analysis.",

keywords = "Aluminum, Chelate, Gallium",

author = "Hill, {Michael S.} and Hutchison, {Aaron R.} and Keizer, {Timothy S.} and Sean Parkin and Vanaelstyn, {Michael A.} and Atwood, {David A.}",

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TY - JOUR

T1 - Monomeric Group 13 compounds with bidentate (N, O) ligands

AU - Hill, Michael S.

AU - Hutchison, Aaron R.

AU - Keizer, Timothy S.

AU - Parkin, Sean

AU - Vanaelstyn, Michael A.

AU - Atwood, David A.

PY - 2001/5/15

Y1 - 2001/5/15

N2 - The bidentate ligand, Sal(tBu)H, is prepared by the condensation of one equivalent of a bulky amine with 3,-5-di-tert-butylsalicylaldehyde. When one equivalent of Sal(tBu)H is added to MR3 or AlMe2Cl, compounds are btained which have the general form: [Sal(tBu)MR2] (with M/R combinations, Al/Me (1), Al/Et (3), Ga/Et (4) and In/Et (5)) and Sal(tBu)AlMeCl (2). The compounds are characterized by melting point, elemental analyses, IR, 1H-NMR, and in the case of 2 and 3 by single-crystal X-ray analysis.

AB - The bidentate ligand, Sal(tBu)H, is prepared by the condensation of one equivalent of a bulky amine with 3,-5-di-tert-butylsalicylaldehyde. When one equivalent of Sal(tBu)H is added to MR3 or AlMe2Cl, compounds are btained which have the general form: [Sal(tBu)MR2] (with M/R combinations, Al/Me (1), Al/Et (3), Ga/Et (4) and In/Et (5)) and Sal(tBu)AlMeCl (2). The compounds are characterized by melting point, elemental analyses, IR, 1H-NMR, and in the case of 2 and 3 by single-crystal X-ray analysis.

KW - Aluminum

KW - Chelate

KW - Gallium

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U2 - 10.1016/S0022-328X(01)00738-0

DO - 10.1016/S0022-328X(01)00738-0

M3 - Article

AN - SCOPUS:0002580076

SN - 0022-328X

VL - 628

SP - 71

EP - 75

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Monomeric Group 13 compounds with bidentate (N, O) ligands

Abstract

Keywords

ASJC Scopus subject areas

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