Monomeric Group 13 compounds with bidentate (N, O) ligands

Michael S. Hill, Aaron R. Hutchison, Timothy S. Keizer, Sean Parkin, Michael A. Vanaelstyn, David A. Atwood

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

The bidentate ligand, Sal(tBu)H, is prepared by the condensation of one equivalent of a bulky amine with 3,-5-di-tert-butylsalicylaldehyde. When one equivalent of Sal(tBu)H is added to MR3 or AlMe2Cl, compounds are btained which have the general form: [Sal(tBu)MR2] (with M/R combinations, Al/Me (1), Al/Et (3), Ga/Et (4) and In/Et (5)) and Sal(tBu)AlMeCl (2). The compounds are characterized by melting point, elemental analyses, IR, 1H-NMR, and in the case of 2 and 3 by single-crystal X-ray analysis.

Original languageEnglish
Pages (from-to)71-75
Number of pages5
JournalJournal of Organometallic Chemistry
Volume628
Issue number1
DOIs
Publication statusPublished - 15 May 2001

Keywords

  • Aluminum
  • Chelate
  • Gallium

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Hill, M. S., Hutchison, A. R., Keizer, T. S., Parkin, S., Vanaelstyn, M. A., & Atwood, D. A. (2001). Monomeric Group 13 compounds with bidentate (N, O) ligands. Journal of Organometallic Chemistry, 628(1), 71-75. https://doi.org/10.1016/S0022-328X(01)00738-0