Molecular structure of novel heterobimetallic thiolate [Cu(PPh3)]4(ZnCl)2(SEt)6.6THF

Gabriele Kociok-Kohn, Kieran C. Molloy, Anna L. Sudlow

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Heterobimetallic thiolate [Cu(PPh3)]4(ZnCl)2 (SEt)6 has been synthesised and characterised by X-ray crystallography as a THF solvate. It contains the first structurally characterised example of a CuI-S(R)-ZnII linkage and only the second species type to embody the CuI-S-ZnII triad.

Original languageEnglish
Pages (from-to)117-119
Number of pages3
JournalMain Group Metal Chemistry
Volume38
Issue number3-4
Early online date23 Jun 2015
DOIs
Publication statusPublished - 1 Aug 2015

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Keywords

  • copper
  • heterobimetallic
  • thiolate
  • X-ray
  • zinc

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